A Self-Folding Metallocavitand

The synthesis and characterization of novel metallocavitand 6 are described. This is a covalent hybrid of a deepened, self-folding cavity and a Zn−phenanthroline fragment. Host 6 features a large molecular cavity of ∼8 × 10 Å dimensions, and the metal binding site is directed in toward the cavity. B...

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Veröffentlicht in:	Journal of the American Chemical Society 2001-10, Vol.123 (41), p.9929-9934
Hauptverfasser:	Lücking, Ulrich, Chen, Jian, Rudkevich, Dmitry M, Rebek, Julius
Format:	Artikel
Sprache:	eng
Schlagworte:	Hydrogen Bonding Magnetic Resonance Spectroscopy Molecular Conformation Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry
Online-Zugang:	Volltext
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