Interconversion between Bis(μ-thiolato)dicopper(II) and Disulfide-Bridged Dicopper(I) Complexes Mediated by Chloride Ion

An unprecedented clean interconversion between a novel bis(μ-thiolato)dicopper(II) complex (1) and a disulfide-bridged dicopper(I) complex (3) through a disulfide-bridged (μ-chloro)dicopper(I) complex (2) mediated by chloride ion has been established for the first time, providing a new redox chemist...

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Veröffentlicht in:	Journal of the American Chemical Society 2002-10, Vol.124 (42), p.12428-12429
Hauptverfasser:	Ueno, Yoshiki, Tachi, Yoshimitsu, Itoh, Shinobu
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Inorganic chemistry and origins of life Kinetics and mechanism of reactions
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	An unprecedented clean interconversion between a novel bis(μ-thiolato)dicopper(II) complex (1) and a disulfide-bridged dicopper(I) complex (3) through a disulfide-bridged (μ-chloro)dicopper(I) complex (2) mediated by chloride ion has been established for the first time, providing a new redox chemistry of the transition metal−sulfur complexes. Crystal structures of 1 and 3 as well as spectroscopic features of the compounds are reported.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja027397m