Tetrakis(2-amino-5-methyl-1,3,4-thiadiazole-N3)chlorocopper(II) chloride monohydrate and tetrakis(2-amino-5-ethyl-1,3,4-thiadiazole-N3)chlorocopper(II) chloride
The structures of the title compounds, [CuCl(C(3)H(5)N(3)S)(4)]Cl.H(2)O, (I), and [CuCl(C(4)H(7)N(3)S)(4)]Cl, (II), comprise square-pyramidal Cu centres with four N-bound organic ligands filling the base positions, a Cl atom in the apical position and a Cl(-) as a free counter-ion. The cation and fr...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2001-09, Vol.57 (Pt 9), p.1032-1035 |
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| container_issue | Pt 9 |
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| container_title | Acta crystallographica. Section C, Crystal structure communications |
| container_volume | 57 |
| creator | LYNCH, Daniel E EWINGTON, Jonathan |
| description | The structures of the title compounds, [CuCl(C(3)H(5)N(3)S)(4)]Cl.H(2)O, (I), and [CuCl(C(4)H(7)N(3)S)(4)]Cl, (II), comprise square-pyramidal Cu centres with four N-bound organic ligands filling the base positions, a Cl atom in the apical position and a Cl(-) as a free counter-ion. The cation and free chloride ion in (II) have fourfold crystallographic symmetry. Hydrogen-bonding associations from the 2-amino H atoms dominate both structures, with the principal acceptors being the chlorides, although in (I), the N4 atoms are also involved. Furthermore, (I) is a hydrate, with the water molecule participating in the hydrogen-bonding network. |
| doi_str_mv | 10.1107/S0108270101009489 |
| format | Article |
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The cation and free chloride ion in (II) have fourfold crystallographic symmetry. Hydrogen-bonding associations from the 2-amino H atoms dominate both structures, with the principal acceptors being the chlorides, although in (I), the N4 atoms are also involved. 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Section C, Crystal structure communications</title><addtitle>Acta Crystallogr C</addtitle><description>The structures of the title compounds, [CuCl(C(3)H(5)N(3)S)(4)]Cl.H(2)O, (I), and [CuCl(C(4)H(7)N(3)S)(4)]Cl, (II), comprise square-pyramidal Cu centres with four N-bound organic ligands filling the base positions, a Cl atom in the apical position and a Cl(-) as a free counter-ion. The cation and free chloride ion in (II) have fourfold crystallographic symmetry. Hydrogen-bonding associations from the 2-amino H atoms dominate both structures, with the principal acceptors being the chlorides, although in (I), the N4 atoms are also involved. Furthermore, (I) is a hydrate, with the water molecule participating in the hydrogen-bonding network.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Copper - chemistry</subject><subject>Crystallography, X-Ray</subject><subject>Exact sciences and technology</subject><subject>Hydrogen Bonding</subject><subject>Inorganic compounds</subject><subject>Metal complexes</subject><subject>Molecular Conformation</subject><subject>Molecular Structure</subject><subject>Organometallic Compounds - chemistry</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>Thiazoles - chemistry</subject><issn>0108-2701</issn><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqdkctKw0AUhgdRbK0-gBvJQqSFjs6ZSTLJUoqXQtGFdR3mFhJNMnUmXdSn8VFNbUChOzfnwPm_821-hM6BXAMQfvNCgCSUdxMIScMkPUBDiAnBEY_SQzTcxnibD9CJ92-EEEopO0YDgChJWAxD9LU0rRPvpR9TLOqysTjCtWmLTYVhyqYhbotS6FJ82srgJzZRRWWdVXa1Mm48n0-Cn0OpTVDbxhYb7URrAtHooN0X_8d7io5yUXlz1u8Rer2_W84e8eL5YT67XWDFaNxiHqa5zFOhlIGcSAlhKGiSJJCHXEQJ0zqnKQtNRAUHlkrKIyW1JFRSpVJj2Ahd7bwrZz_WxrdZXXplqko0xq59xilwTsO4A2EHKme9dybPVq6shdtkQLJtLdleLd3PRS9fy9ro34--hw647AHhlahyJxpV-j8cIXFE2Tc3U5SV</recordid><startdate>20010901</startdate><enddate>20010901</enddate><creator>LYNCH, Daniel E</creator><creator>EWINGTON, Jonathan</creator><general>Blackwell</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20010901</creationdate><title>Tetrakis(2-amino-5-methyl-1,3,4-thiadiazole-N3)chlorocopper(II) chloride monohydrate and tetrakis(2-amino-5-ethyl-1,3,4-thiadiazole-N3)chlorocopper(II) chloride</title><author>LYNCH, Daniel E ; EWINGTON, Jonathan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c326t-749fbf9acce1f0bb144a28881f47a583ddf2934e52a7139b275cbdb02b2cc9ee3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Copper - chemistry</topic><topic>Crystallography, X-Ray</topic><topic>Exact sciences and technology</topic><topic>Hydrogen Bonding</topic><topic>Inorganic compounds</topic><topic>Metal complexes</topic><topic>Molecular Conformation</topic><topic>Molecular Structure</topic><topic>Organometallic Compounds - chemistry</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>Thiazoles - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>LYNCH, Daniel E</creatorcontrib><creatorcontrib>EWINGTON, Jonathan</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>LYNCH, Daniel E</au><au>EWINGTON, Jonathan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tetrakis(2-amino-5-methyl-1,3,4-thiadiazole-N3)chlorocopper(II) chloride monohydrate and tetrakis(2-amino-5-ethyl-1,3,4-thiadiazole-N3)chlorocopper(II) chloride</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Crystallogr C</addtitle><date>2001-09-01</date><risdate>2001</risdate><volume>57</volume><issue>Pt 9</issue><spage>1032</spage><epage>1035</epage><pages>1032-1035</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><coden>ACSCEE</coden><abstract>The structures of the title compounds, [CuCl(C(3)H(5)N(3)S)(4)]Cl.H(2)O, (I), and [CuCl(C(4)H(7)N(3)S)(4)]Cl, (II), comprise square-pyramidal Cu centres with four N-bound organic ligands filling the base positions, a Cl atom in the apical position and a Cl(-) as a free counter-ion. The cation and free chloride ion in (II) have fourfold crystallographic symmetry. Hydrogen-bonding associations from the 2-amino H atoms dominate both structures, with the principal acceptors being the chlorides, although in (I), the N4 atoms are also involved. Furthermore, (I) is a hydrate, with the water molecule participating in the hydrogen-bonding network.</abstract><cop>Oxford</cop><pub>Blackwell</pub><pmid>11588361</pmid><doi>10.1107/S0108270101009489</doi><tpages>4</tpages></addata></record> |
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| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2001-09, Vol.57 (Pt 9), p.1032-1035 |
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| source | MEDLINE; Crystallography Journals Online; Wiley Online Library All Journals |
| subjects | Condensed matter: structure, mechanical and thermal properties Copper - chemistry Crystallography, X-Ray Exact sciences and technology Hydrogen Bonding Inorganic compounds Metal complexes Molecular Conformation Molecular Structure Organometallic Compounds - chemistry Physics Structure of solids and liquids crystallography Structure of specific crystalline solids Thiazoles - chemistry |
| title | Tetrakis(2-amino-5-methyl-1,3,4-thiadiazole-N3)chlorocopper(II) chloride monohydrate and tetrakis(2-amino-5-ethyl-1,3,4-thiadiazole-N3)chlorocopper(II) chloride |
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