A New Route to Coordination Complexes of Nitroxyl (HNO) via Insertion Reactions of Nitrosonium Triflate with Transition-Metal Hydrides

Nitrosonium triflate reacts with cold methylene chloride solutions of mer,trans-ReH(CO)3(PPh3)2 (1) with 1,1-insertion of NO+ into the Re−H bond to give the orange nitroxyl complex [mer,trans-Re(NHO)(CO)3(PPh3)2][SO3CF3] (3) in 86% isolated yield. Use of [NO][PF6] or [NO][BF4] gives analogous inser...

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Veröffentlicht in:	Journal of the American Chemical Society 2002-10, Vol.124 (41), p.12068-12069
Hauptverfasser:	Melenkivitz, Rory, Southern, Joel S, Hillhouse, Gregory L, Concolino, Thomas E, Liable-Sands, Louise M, Rheingold, Arnold L
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Inorganic chemistry and origins of life Kinetics and mechanism of reactions
Online-Zugang:	Volltext
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