Synthesis of Allyl Cyanamides and N-Cyanoindoles via the Palladium-Catalyzed Three-Component Coupling Reaction

The palladium-catalyzed three-component coupling reaction (TCCR) of aryl isocyanides, allyl methyl carbonate, and trimethylsilyl azide was conducted in the presence of Pd2(dba)3·CHCl3 (2.5 mol %) and dppe (1,2-bis(diphenylphosphino)ethane) (10 mol %). Allyl aryl cyanamides with a wide variety of fun...

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Veröffentlicht in:	Journal of the American Chemical Society 2002-10, Vol.124 (40), p.11940-11945
Hauptverfasser:	Kamijo, Shin, Yamamoto, Yoshinori
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography, X-Ray Cyanamide - chemical synthesis Cyanamide - chemistry Cyanides - chemical synthesis Cyanides - chemistry Indoles - chemical synthesis Indoles - chemistry Molecular Structure Palladium - chemistry
Online-Zugang:	Volltext
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