A general method for convergent synthesis of functionalized exo-glycals based on halogenation and Suzuki cross-coupling of 1-exo-methylene sugars

A general method for convergent synthesis of functionalized exo-glycals based on halogenation and Suzuki cross-coupling of 1-exo-methylene sugars

Functionalized exo-glycals can be readily obtained by palladium catalyzed Suzuki cross-coupling of halo-exo-glycals with boronic acids.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-01 (18), p.2024-2025
Hauptverfasser: Gómez, Ana M, Danelón, Gerardo O, Pedregosa, Ana, Valverde, Serafín, López, J Cristóbal
Format: Artikel
Sprache:eng
Schlagworte:
Carbohydrates - chemical synthesis
Glycosides - chemistry
Hydrocarbons, Brominated - chemical synthesis
Stereoisomerism
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Zusammenfassung:Functionalized exo-glycals can be readily obtained by palladium catalyzed Suzuki cross-coupling of halo-exo-glycals with boronic acids.
ISSN:1359-7345
1364-548X
DOI:10.1039/b205121d