Control of the stoichiometry in host-guest complexation by redox chemistry of guests: inclusion of methylviologen in cucurbit[8]uril
The binding stoichiometry of a host-guest complex can be effectively controlled by the redox chemistry of the guest: a 1:1 inclusion complex of methylviologen dication (MV2+) in cucurbit[8]uril (CB[8]) converts completely and reversibly to a 2:1 inclusion complex of cation radical (MV+.) in CB[8] up...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2002-01 (17), p.1828-1829 |
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| container_end_page | 1829 |
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| container_issue | 17 |
| container_start_page | 1828 |
| container_title | Chemical communications (Cambridge, England) |
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| creator | Jeon, Woo Sung Kim, Hee-Joon Lee, Chongmok Kim, Kimoon |
| description | The binding stoichiometry of a host-guest complex can be effectively controlled by the redox chemistry of the guest: a 1:1 inclusion complex of methylviologen dication (MV2+) in cucurbit[8]uril (CB[8]) converts completely and reversibly to a 2:1 inclusion complex of cation radical (MV+.) in CB[8] upon the reduction of the guest. |
| doi_str_mv | 10.1039/b202082c |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2002-01 (17), p.1828-1829 |
| issn | 1359-7345 1364-548X 1364-548X |
| language | eng |
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| source | Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | cations chemical reactions macrocyclic compounds stoichiometry |
| title | Control of the stoichiometry in host-guest complexation by redox chemistry of guests: inclusion of methylviologen in cucurbit[8]uril |
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