Activation energies and formation rate constants for organic arsenical-antidote adducts as determined by dynamic NMR spectroscopy

Phenyldichloroarsine reacts with 1,3-dimercapto-2-propanol and 1,2-dimercaptopropane to form 1:1 adducts in the form of a six-membered and five-membered heteroatom rings. Two geometric isomers for each compound are present in dynamic equilibrium. Rate constants and the activation barriers for the in...

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Veröffentlicht in:	Chemical research in toxicology 1991-05, Vol.4 (3), p.295-299
Hauptverfasser:	Dill, Kilian, Huang, Lihua, Bearden, Daniel W, McGown, Evelyn L, O'Connor, Richard J
Format:	Artikel
Sprache:	eng
Schlagworte:	Antidotes - chemistry Arsenicals - chemistry Biological and medical sciences Chemical and industrial products toxicology. Toxic occupational diseases Glycerol - analogs & derivatives Glycerol - chemistry Kinetics Magnetic Resonance Spectroscopy - methods Medical sciences Metals and various inorganic compounds Molecular Conformation Propane - analogs & derivatives Propane - chemistry Spectrum Analysis - methods Sulfhydryl Compounds - chemistry Thermodynamics Toxicology
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