Determination of nonylphenol polyethoxylates in household detergents by high-performance liquid chromatography
Preliminary survey results of the content of nonylphenol polyethoxylates (NPEOs) in various household detergents sold in Taiwan are presented. This survey was conducted to elucidate the concentration of NPEOs in household detergents and support pollution prevention and control programs. The concentr...
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Veröffentlicht in: | Journal of Chromatography A 2002-08, Vol.968 (1), p.143-150 |
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description | Preliminary survey results of the content of nonylphenol polyethoxylates (NPEOs) in various household detergents sold in Taiwan are presented. This survey was conducted to elucidate the concentration of NPEOs in household detergents and support pollution prevention and control programs. The concentrations of NPEOs in detergents and cleaners were determined by HPLC with a C
8 reversed-phase column and equipped with fluorescence detection. The accuracy and precision of the method was validated and was successfully applied to determine concentrations of NPEOs in household detergents. The results show that NPEOs were detected in 41% of 90 household detergents at concentrations from 0.2 to 21%. The highest concentration of NPEOs (21%) was detected in a laundry liquid especially designed for washing socks. Reversed-phase liquid chromatography connected with electrospray mass spectrometry confirmed the results. |
doi_str_mv | 10.1016/S0021-9673(02)00959-7 |
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8 reversed-phase column and equipped with fluorescence detection. The accuracy and precision of the method was validated and was successfully applied to determine concentrations of NPEOs in household detergents. The results show that NPEOs were detected in 41% of 90 household detergents at concentrations from 0.2 to 21%. The highest concentration of NPEOs (21%) was detected in a laundry liquid especially designed for washing socks. Reversed-phase liquid chromatography connected with electrospray mass spectrometry confirmed the results.</description><identifier>ISSN: 0021-9673</identifier><identifier>DOI: 10.1016/S0021-9673(02)00959-7</identifier><identifier>PMID: 12236497</identifier><identifier>CODEN: JOCRAM</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Chemical industry and chemicals ; Chromatography, High Pressure Liquid - methods ; Detergents - analysis ; Ethoxylates ; Ethylene Glycols - analysis ; Exact sciences and technology ; Nonylphenol ethoxylates ; Reproducibility of Results ; Spectrometry, Fluorescence ; Spectrometry, Mass, Electrospray Ionization ; Surfactants ; Washing products ; Washing products. Cosmetics and toiletries. Perfumes</subject><ispartof>Journal of Chromatography A, 2002-08, Vol.968 (1), p.143-150</ispartof><rights>2002 Elsevier Science B.V.</rights><rights>2002 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c391t-e98a98d5b0bd20c9af880c674f23f0798f65430ae2af908fdceb7355c6c25dd93</citedby><cites>FETCH-LOGICAL-c391t-e98a98d5b0bd20c9af880c674f23f0798f65430ae2af908fdceb7355c6c25dd93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0021-9673(02)00959-7$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27911,27912,45982</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=13848776$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/12236497$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Cheng, Chin-Yuan</creatorcontrib><creatorcontrib>Ding, Wang-Hsien</creatorcontrib><title>Determination of nonylphenol polyethoxylates in household detergents by high-performance liquid chromatography</title><title>Journal of Chromatography A</title><addtitle>J Chromatogr A</addtitle><description>Preliminary survey results of the content of nonylphenol polyethoxylates (NPEOs) in various household detergents sold in Taiwan are presented. This survey was conducted to elucidate the concentration of NPEOs in household detergents and support pollution prevention and control programs. The concentrations of NPEOs in detergents and cleaners were determined by HPLC with a C
8 reversed-phase column and equipped with fluorescence detection. The accuracy and precision of the method was validated and was successfully applied to determine concentrations of NPEOs in household detergents. The results show that NPEOs were detected in 41% of 90 household detergents at concentrations from 0.2 to 21%. The highest concentration of NPEOs (21%) was detected in a laundry liquid especially designed for washing socks. Reversed-phase liquid chromatography connected with electrospray mass spectrometry confirmed the results.</description><subject>Applied sciences</subject><subject>Chemical industry and chemicals</subject><subject>Chromatography, High Pressure Liquid - methods</subject><subject>Detergents - analysis</subject><subject>Ethoxylates</subject><subject>Ethylene Glycols - analysis</subject><subject>Exact sciences and technology</subject><subject>Nonylphenol ethoxylates</subject><subject>Reproducibility of Results</subject><subject>Spectrometry, Fluorescence</subject><subject>Spectrometry, Mass, Electrospray Ionization</subject><subject>Surfactants</subject><subject>Washing products</subject><subject>Washing products. Cosmetics and toiletries. Perfumes</subject><issn>0021-9673</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkEtv1TAQRr0A0VL4CSBvQLAInTgP2yuEyqOVKnUBrC3HHt8YOXZq5yLy78ntvaJLViONzjePQ8irGj7UUPeX3wFYXcmeN--AvQeQnaz4E3L-r31GnpfyC6DmwNkzclYz1vSt5OckfsYF8-SjXnyKNDkaU1zDPGJMgc4prLiM6c8a9IKF-kjHtC84pmCpPSR3GJdCh5WOfjdWM2aX8qSjQRr8_d5basacJr2kXdbzuL4gT50OBV-e6gX5-fXLj6vr6vbu283Vp9vKNLJeKpRCS2G7AQbLwEjthADT89axxgGXwvVd24BGpp0E4azBgTddZ3rDOmtlc0HeHufOOd3vsSxq8sVgCDri9oDirIYWxAHsjqDJqZSMTs3ZTzqvqgZ1kKse5KqDRQVMPchVfMu9Pi3YDxPax9TJ7Aa8OQG6GB1c3qT48sg1ohWc9xv38cjhpuO3x6yK8bgJtD6jWZRN_j-n_AXWtZwE</recordid><startdate>20020830</startdate><enddate>20020830</enddate><creator>Cheng, Chin-Yuan</creator><creator>Ding, Wang-Hsien</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20020830</creationdate><title>Determination of nonylphenol polyethoxylates in household detergents by high-performance liquid chromatography</title><author>Cheng, Chin-Yuan ; Ding, Wang-Hsien</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c391t-e98a98d5b0bd20c9af880c674f23f0798f65430ae2af908fdceb7355c6c25dd93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Applied sciences</topic><topic>Chemical industry and chemicals</topic><topic>Chromatography, High Pressure Liquid - methods</topic><topic>Detergents - analysis</topic><topic>Ethoxylates</topic><topic>Ethylene Glycols - analysis</topic><topic>Exact sciences and technology</topic><topic>Nonylphenol ethoxylates</topic><topic>Reproducibility of Results</topic><topic>Spectrometry, Fluorescence</topic><topic>Spectrometry, Mass, Electrospray Ionization</topic><topic>Surfactants</topic><topic>Washing products</topic><topic>Washing products. Cosmetics and toiletries. Perfumes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cheng, Chin-Yuan</creatorcontrib><creatorcontrib>Ding, Wang-Hsien</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of Chromatography A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cheng, Chin-Yuan</au><au>Ding, Wang-Hsien</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of nonylphenol polyethoxylates in household detergents by high-performance liquid chromatography</atitle><jtitle>Journal of Chromatography A</jtitle><addtitle>J Chromatogr A</addtitle><date>2002-08-30</date><risdate>2002</risdate><volume>968</volume><issue>1</issue><spage>143</spage><epage>150</epage><pages>143-150</pages><issn>0021-9673</issn><coden>JOCRAM</coden><abstract>Preliminary survey results of the content of nonylphenol polyethoxylates (NPEOs) in various household detergents sold in Taiwan are presented. This survey was conducted to elucidate the concentration of NPEOs in household detergents and support pollution prevention and control programs. The concentrations of NPEOs in detergents and cleaners were determined by HPLC with a C
8 reversed-phase column and equipped with fluorescence detection. The accuracy and precision of the method was validated and was successfully applied to determine concentrations of NPEOs in household detergents. The results show that NPEOs were detected in 41% of 90 household detergents at concentrations from 0.2 to 21%. The highest concentration of NPEOs (21%) was detected in a laundry liquid especially designed for washing socks. Reversed-phase liquid chromatography connected with electrospray mass spectrometry confirmed the results.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>12236497</pmid><doi>10.1016/S0021-9673(02)00959-7</doi><tpages>8</tpages></addata></record> |
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subjects | Applied sciences Chemical industry and chemicals Chromatography, High Pressure Liquid - methods Detergents - analysis Ethoxylates Ethylene Glycols - analysis Exact sciences and technology Nonylphenol ethoxylates Reproducibility of Results Spectrometry, Fluorescence Spectrometry, Mass, Electrospray Ionization Surfactants Washing products Washing products. Cosmetics and toiletries. Perfumes |
title | Determination of nonylphenol polyethoxylates in household detergents by high-performance liquid chromatography |
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