Estimation of soil organic partition coefficients: from retention factors measured by soil column chromatography with water as eluent
The retention factors ( k) of 104 hydrophobic organic chemicals (HOCs) were measured in soil column chromatography (SCC) over columns filled with three naturally occurring reference soils and eluted with Milli-Q water. A novel method for the estimation of soil organic partition coefficient ( K oc) w...
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| Veröffentlicht in: | Journal of Chromatography A 2002-08, Vol.968 (1), p.7-16 |
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| container_title | Journal of Chromatography A |
| container_volume | 968 |
| creator | Xu, Feng Liang, Xinmiao Lin, Bingcheng Schramm, Karl-Werner Kettrup, Antonius |
| description | The retention factors (
k) of 104 hydrophobic organic chemicals (HOCs) were measured in soil column chromatography (SCC) over columns filled with three naturally occurring reference soils and eluted with Milli-Q water. A novel method for the estimation of soil organic partition coefficient (
K
oc) was developed based on correlations with
k in soil/water systems. Strong log
K
oc versus log
k correlations (
r>0.96) were found. The estimated
K
oc values were in accordance with the literature values with a maximum deviation of less than 0.4 log units. All estimated
K
oc values from three soils were consistent with each other. The SCC approach is promising for fast screening of a large number of chemicals in their environmental applications. |
| doi_str_mv | 10.1016/S0021-9673(02)00821-X |
| format | Article |
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k) of 104 hydrophobic organic chemicals (HOCs) were measured in soil column chromatography (SCC) over columns filled with three naturally occurring reference soils and eluted with Milli-Q water. A novel method for the estimation of soil organic partition coefficient (
K
oc) was developed based on correlations with
k in soil/water systems. Strong log
K
oc versus log
k correlations (
r>0.96) were found. The estimated
K
oc values were in accordance with the literature values with a maximum deviation of less than 0.4 log units. All estimated
K
oc values from three soils were consistent with each other. The SCC approach is promising for fast screening of a large number of chemicals in their environmental applications.</description><identifier>ISSN: 0021-9673</identifier><identifier>DOI: 10.1016/S0021-9673(02)00821-X</identifier><identifier>PMID: 12236516</identifier><identifier>CODEN: JOCRAM</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Agronomy. Soil science and plant productions ; Applied sciences ; Biological and medical sciences ; Biological and physicochemical properties of pollutants. Interaction in the soil ; Exact sciences and technology ; Fundamental and applied biological sciences. Psychology ; Hydrophobic organic compounds ; Organic Chemicals - chemistry ; Pollution ; Soil ; Soil and sediments pollution ; Soil and water pollution ; Soil science ; Water - chemistry</subject><ispartof>Journal of Chromatography A, 2002-08, Vol.968 (1), p.7-16</ispartof><rights>2002 Elsevier Science B.V.</rights><rights>2002 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c391t-667e34b37131f5cd32af11863c165b64a200bf2722ff83435e229e5d421fd1d13</citedby><cites>FETCH-LOGICAL-c391t-667e34b37131f5cd32af11863c165b64a200bf2722ff83435e229e5d421fd1d13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S002196730200821X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=13848763$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/12236516$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Xu, Feng</creatorcontrib><creatorcontrib>Liang, Xinmiao</creatorcontrib><creatorcontrib>Lin, Bingcheng</creatorcontrib><creatorcontrib>Schramm, Karl-Werner</creatorcontrib><creatorcontrib>Kettrup, Antonius</creatorcontrib><title>Estimation of soil organic partition coefficients: from retention factors measured by soil column chromatography with water as eluent</title><title>Journal of Chromatography A</title><addtitle>J Chromatogr A</addtitle><description>The retention factors (
k) of 104 hydrophobic organic chemicals (HOCs) were measured in soil column chromatography (SCC) over columns filled with three naturally occurring reference soils and eluted with Milli-Q water. A novel method for the estimation of soil organic partition coefficient (
K
oc) was developed based on correlations with
k in soil/water systems. Strong log
K
oc versus log
k correlations (
r>0.96) were found. The estimated
K
oc values were in accordance with the literature values with a maximum deviation of less than 0.4 log units. All estimated
K
oc values from three soils were consistent with each other. The SCC approach is promising for fast screening of a large number of chemicals in their environmental applications.</description><subject>Agronomy. Soil science and plant productions</subject><subject>Applied sciences</subject><subject>Biological and medical sciences</subject><subject>Biological and physicochemical properties of pollutants. Interaction in the soil</subject><subject>Exact sciences and technology</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Hydrophobic organic compounds</subject><subject>Organic Chemicals - chemistry</subject><subject>Pollution</subject><subject>Soil</subject><subject>Soil and sediments pollution</subject><subject>Soil and water pollution</subject><subject>Soil science</subject><subject>Water - chemistry</subject><issn>0021-9673</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkM1u1DAURr0oakvLI7TyBgSLAV87cTJsEKpKi1SJBSB1ZznOdcdVEg--DtU8AO-N50d0ycq6vuf7bB3GLkC8BwH6w3chJCyWulFvhXwnRFum-yN2-u_6hL0kehQCGtHIY3YCUipdgz5lf64ph9HmECcePacYBh7Tg52C42ubcthtXETvgws4ZfrIfYojT5jLtF1663JMxEe0NCfsebfZ97g4zGMJrwpvc3xIdr3a8KeQV_zJZkzcEsdhLjXn7IW3A-Grw3nGfn65_nF1u7j7dvP16vPdwqkl5IXWDaqqUw0o8LXrlbQeoNXKga47XVkpROdlI6X3rapUjVIuse4rCb6HHtQZe7PvXaf4a0bKZgzkcBjshHEm00gQslgqYL0HXYpECb1Zp6IpbQwIs3Vuds7NVq4R0uycm_uSuzw8MHcj9s-pg_ACvD4AlpwdfLKTC_TMqbZqG60K92nPYdHxO2AytNXvsA8JXTZ9DP_5yl8AB6Kb</recordid><startdate>20020830</startdate><enddate>20020830</enddate><creator>Xu, Feng</creator><creator>Liang, Xinmiao</creator><creator>Lin, Bingcheng</creator><creator>Schramm, Karl-Werner</creator><creator>Kettrup, Antonius</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20020830</creationdate><title>Estimation of soil organic partition coefficients: from retention factors measured by soil column chromatography with water as eluent</title><author>Xu, Feng ; Liang, Xinmiao ; Lin, Bingcheng ; Schramm, Karl-Werner ; Kettrup, Antonius</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c391t-667e34b37131f5cd32af11863c165b64a200bf2722ff83435e229e5d421fd1d13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Agronomy. Soil science and plant productions</topic><topic>Applied sciences</topic><topic>Biological and medical sciences</topic><topic>Biological and physicochemical properties of pollutants. Interaction in the soil</topic><topic>Exact sciences and technology</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Hydrophobic organic compounds</topic><topic>Organic Chemicals - chemistry</topic><topic>Pollution</topic><topic>Soil</topic><topic>Soil and sediments pollution</topic><topic>Soil and water pollution</topic><topic>Soil science</topic><topic>Water - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Feng</creatorcontrib><creatorcontrib>Liang, Xinmiao</creatorcontrib><creatorcontrib>Lin, Bingcheng</creatorcontrib><creatorcontrib>Schramm, Karl-Werner</creatorcontrib><creatorcontrib>Kettrup, Antonius</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of Chromatography A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Feng</au><au>Liang, Xinmiao</au><au>Lin, Bingcheng</au><au>Schramm, Karl-Werner</au><au>Kettrup, Antonius</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Estimation of soil organic partition coefficients: from retention factors measured by soil column chromatography with water as eluent</atitle><jtitle>Journal of Chromatography A</jtitle><addtitle>J Chromatogr A</addtitle><date>2002-08-30</date><risdate>2002</risdate><volume>968</volume><issue>1</issue><spage>7</spage><epage>16</epage><pages>7-16</pages><issn>0021-9673</issn><coden>JOCRAM</coden><abstract>The retention factors (
k) of 104 hydrophobic organic chemicals (HOCs) were measured in soil column chromatography (SCC) over columns filled with three naturally occurring reference soils and eluted with Milli-Q water. A novel method for the estimation of soil organic partition coefficient (
K
oc) was developed based on correlations with
k in soil/water systems. Strong log
K
oc versus log
k correlations (
r>0.96) were found. The estimated
K
oc values were in accordance with the literature values with a maximum deviation of less than 0.4 log units. All estimated
K
oc values from three soils were consistent with each other. The SCC approach is promising for fast screening of a large number of chemicals in their environmental applications.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>12236516</pmid><doi>10.1016/S0021-9673(02)00821-X</doi><tpages>10</tpages></addata></record> |
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| ispartof | Journal of Chromatography A, 2002-08, Vol.968 (1), p.7-16 |
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| source | MEDLINE; Elsevier ScienceDirect Journals |
| subjects | Agronomy. Soil science and plant productions Applied sciences Biological and medical sciences Biological and physicochemical properties of pollutants. Interaction in the soil Exact sciences and technology Fundamental and applied biological sciences. Psychology Hydrophobic organic compounds Organic Chemicals - chemistry Pollution Soil Soil and sediments pollution Soil and water pollution Soil science Water - chemistry |
| title | Estimation of soil organic partition coefficients: from retention factors measured by soil column chromatography with water as eluent |
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