Zwitterionic Ring-Borylated ansa-Chromocene Complexes
Ring borylation of [Me4C2(eta5-C5H4)2CrCO] by B(C6F5)3 affords the zwitterionic complex {Me4(eta5-C5H4)(eta5-C4H3B(C6F5)3)}CrH(CO) (1), the first structurally characterized bent-metallocene complex of Cr(4+). This species decomposes thermally to the zwitterionic species {Me4(eta5-C5H4)(eta5-C4H3B(C6...
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| Veröffentlicht in: | Journal of the American Chemical Society 2002-09, Vol.124 (37), p.10996-10997 |
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| container_issue | 37 |
| container_start_page | 10996 |
| container_title | Journal of the American Chemical Society |
| container_volume | 124 |
| creator | SINNEMA, Piet-Jan SHAPIRO, Pamela J. FOO, David Min Jin TWAMLEY, Brendan |
| description | Ring borylation of [Me4C2(eta5-C5H4)2CrCO] by B(C6F5)3 affords the zwitterionic complex {Me4(eta5-C5H4)(eta5-C4H3B(C6F5)3)}CrH(CO) (1), the first structurally characterized bent-metallocene complex of Cr(4+). This species decomposes thermally to the zwitterionic species {Me4(eta5-C5H4)(eta5-C4H3B(C6F5)3)}Cr (2) and the ionic species [Me4C2(eta5-C5H4)2CrCO][HB(C6F5)3] (3). The molecular structure of 2 is also described. |
| doi_str_mv | 10.1021/ja026633q |
| format | Article |
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This species decomposes thermally to the zwitterionic species {Me4(eta5-C5H4)(eta5-C4H3B(C6F5)3)}Cr (2) and the ionic species [Me4C2(eta5-C5H4)2CrCO][HB(C6F5)3] (3). The molecular structure of 2 is also described.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja026633q</identifier><identifier>PMID: 12224944</identifier><identifier>CODEN: JACSAT</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Organic chemistry ; Organic compounds ; Organometalloidal and organometallic compounds ; Physics ; Preparations and properties ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; Transition metals derivatives</subject><ispartof>Journal of the American Chemical Society, 2002-09, Vol.124 (37), p.10996-10997</ispartof><rights>2003 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=13920541$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/12224944$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>SINNEMA, Piet-Jan</creatorcontrib><creatorcontrib>SHAPIRO, Pamela J.</creatorcontrib><creatorcontrib>FOO, David Min Jin</creatorcontrib><creatorcontrib>TWAMLEY, Brendan</creatorcontrib><title>Zwitterionic Ring-Borylated ansa-Chromocene Complexes</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>Ring borylation of [Me4C2(eta5-C5H4)2CrCO] by B(C6F5)3 affords the zwitterionic complex {Me4(eta5-C5H4)(eta5-C4H3B(C6F5)3)}CrH(CO) (1), the first structurally characterized bent-metallocene complex of Cr(4+). This species decomposes thermally to the zwitterionic species {Me4(eta5-C5H4)(eta5-C4H3B(C6F5)3)}Cr (2) and the ionic species [Me4C2(eta5-C5H4)2CrCO][HB(C6F5)3] (3). The molecular structure of 2 is also described.</description><subject>Chemistry</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Organic chemistry</subject><subject>Organic compounds</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Physics</subject><subject>Preparations and properties</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>Transition metals derivatives</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNpFz8tOwzAQBVALgWgpLPgB1A3sDH4kdrKEFApVEa8iITaWm4zBkMStnYr274logdVoNEdXdxA6pOSUEkbPPjRhQnA-30JdGjOCY8rENuoSQhiWieAdtBfCR7tGLKG7qEMZY1EaRV0Uv37ZpgFvXW3z_qOt3_CF86tSN1D0dR00zt69q1wONfQzV81KWELYRztGlwEONrOHnq8uJ9k1Ht8Nb7LzMbZMxg2WhJJimqdiSiBJ44hqMFJGCReSyzihgtI4MgCESSMEaK5NmkhRcGAgDBW8h07WuTPv5gsIjapsyKEsdQ1uEZRkRCY8JS082sDFtIJCzbyttF-p30dbcLwBOuS6NF7XuQ3_jqeMtAVbh9fOhgaWf3ftP9VPaTW5f1Ivo-HgYXAr1Ih_AzMKbsI</recordid><startdate>20020918</startdate><enddate>20020918</enddate><creator>SINNEMA, Piet-Jan</creator><creator>SHAPIRO, Pamela J.</creator><creator>FOO, David Min Jin</creator><creator>TWAMLEY, Brendan</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>7X8</scope></search><sort><creationdate>20020918</creationdate><title>Zwitterionic Ring-Borylated ansa-Chromocene Complexes</title><author>SINNEMA, Piet-Jan ; SHAPIRO, Pamela J. ; FOO, David Min Jin ; TWAMLEY, Brendan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i275t-7010dbc96b0e89541aef77483673758161154fee027f66ea3af9876d3e2e6f163</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Chemistry</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Organic chemistry</topic><topic>Organic compounds</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Physics</topic><topic>Preparations and properties</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>Transition metals derivatives</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>SINNEMA, Piet-Jan</creatorcontrib><creatorcontrib>SHAPIRO, Pamela J.</creatorcontrib><creatorcontrib>FOO, David Min Jin</creatorcontrib><creatorcontrib>TWAMLEY, Brendan</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>SINNEMA, Piet-Jan</au><au>SHAPIRO, Pamela J.</au><au>FOO, David Min Jin</au><au>TWAMLEY, Brendan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zwitterionic Ring-Borylated ansa-Chromocene Complexes</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2002-09-18</date><risdate>2002</risdate><volume>124</volume><issue>37</issue><spage>10996</spage><epage>10997</epage><pages>10996-10997</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>Ring borylation of [Me4C2(eta5-C5H4)2CrCO] by B(C6F5)3 affords the zwitterionic complex {Me4(eta5-C5H4)(eta5-C4H3B(C6F5)3)}CrH(CO) (1), the first structurally characterized bent-metallocene complex of Cr(4+). This species decomposes thermally to the zwitterionic species {Me4(eta5-C5H4)(eta5-C4H3B(C6F5)3)}Cr (2) and the ionic species [Me4C2(eta5-C5H4)2CrCO][HB(C6F5)3] (3). The molecular structure of 2 is also described.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>12224944</pmid><doi>10.1021/ja026633q</doi><tpages>2</tpages></addata></record> |
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| source | American Chemical Society Journals |
| subjects | Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic chemistry Organic compounds Organometalloidal and organometallic compounds Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids Transition metals derivatives |
| title | Zwitterionic Ring-Borylated ansa-Chromocene Complexes |
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