Asymmetric Baeyer-Villiger Reaction with Hydrogen Peroxide Catalyzed by a Novel Planar-Chiral Bisflavin
The chiral organocatalyst bisflavin 1 catalyzes the asymmetric Baeyer–Villiger reaction of cyclobutanones with H2O2 (see scheme). The corresponding lactones are obtained with up to 74 % ee.
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| Veröffentlicht in: | Angewandte Chemie International Edition 2002-07, Vol.41 (13), p.2366-2368 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Murahashi, Shun-Ichi Ono, Satoshi Imada, Yasushi |
| description | The chiral organocatalyst bisflavin 1 catalyzes the asymmetric Baeyer–Villiger reaction of cyclobutanones with H2O2 (see scheme). The corresponding lactones are obtained with up to 74 % ee. |
| doi_str_mv | 10.1002/1521-3773(20020703)41:13<2366::AID-ANIE2366>3.0.CO;2-S |
| format | Article |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | asymmetric catalysis biomimetic synthesis enantioselectivity lactones oxidation |
| title | Asymmetric Baeyer-Villiger Reaction with Hydrogen Peroxide Catalyzed by a Novel Planar-Chiral Bisflavin |
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