Mechanisms of Sulfanyl (RS) Migrations: Synthesis of Heterocycles

Thiiranium (episulfonium) ions had been acknowledged as reaction intermediates for many years, but it was not until 1977 that Nicolaou demonstrated systematically that these reactive heterocyclic cations could be trapped by carboxylic acids to give lactones. In the years that followed this report, e...

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Veröffentlicht in:	Angewandte Chemie International Edition 2002-07, Vol.41 (14), p.2462-2482
Hauptverfasser:	Fox, David J., House, David, Warren, Stuart
Format:	Artikel
Sprache:	eng
Schlagworte:	cyclization heterocycles rearrangement sulfanyl groups thiiranium ions
Online-Zugang:	Volltext
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