A New Method for the Preparation of Silyl Enol Ethers from Carbonyl Compounds and (Trimethylsilyl)diazomethane in a Regiospecific and Highly Stereoselective Manner

The reaction of lithium (trimethylsilyl)diazomethane with aldehydes and ketones has been investigated, and it has been found that quenching at low temperature with MeOH followed by addition of Rh2(OAc)4 gave silyl enol ethers in high yields. Quenching with other electrophiles (e.g., deuterium, MeI)...

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Veröffentlicht in:	Journal of the American Chemical Society 2002-09, Vol.124 (35), p.10300-10301
Hauptverfasser:	Aggarwal, Varinder K, Sheldon, Chris G, Macdonald, Gregor J, Martin, William P
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Organic chemistry
Online-Zugang:	Volltext
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