New Clathrate Hydrate Structure: High-Pressure Tetrahydrofuran Hydrate with One Type of Cavity
Water cages: A water framework consisting of uniform space‐filling polyhedral cages containing tetrahydrofuran molecules has been detected in a new clathrate hydrate formed under a pressure of 0.8 GPa. Topologically the cage represents a space‐filling tetradecahedron with four tetra‐, four penta‐, a...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2004-05, Vol.43 (22), p.2922-2924 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Kurnosov, Alexander V. Komarov, Vladislav Yu Voronin, Vladimir I. Teplykh, Alexander E. Manakov, Andrej Yu |
| description | Water cages: A water framework consisting of uniform space‐filling polyhedral cages containing tetrahydrofuran molecules has been detected in a new clathrate hydrate formed under a pressure of 0.8 GPa. Topologically the cage represents a space‐filling tetradecahedron with four tetra‐, four penta‐, and six hexagonal faces (see picture). |
| doi_str_mv | 10.1002/anie.200453712 |
| format | Article |
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| subjects | clathrates high-pressure chemistry host-guest systems hydrates neutron diffraction |
| title | New Clathrate Hydrate Structure: High-Pressure Tetrahydrofuran Hydrate with One Type of Cavity |
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