A New Type of Material for the Recovery of Hydrogen from Gas Mixtures

A New Type of Material for the Recovery of Hydrogen from Gas Mixtures

Molecular gas works: p‐tert‐Butylcalix[4]arene crystals possess large interstitial cavities when grown by sublimation and, although nonporous, are able to absorb and retain gases such as O2, N2, and CO2 under near‐ambient conditions. H2 is not retained and thus the material can be used to effect the...

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Veröffentlicht in:Angewandte Chemie International Edition 2004-05, Vol.43 (22), p.2948-2950
Hauptverfasser: Atwood, Jerry L., Barbour, Leonard J., Jerga, Agoston
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Sprache:eng
Schlagworte:
absorption
calixarenes
host-guest systems
hydrogen
inclusion compounds
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container_title Angewandte Chemie International Edition
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creator Atwood, Jerry L.
Barbour, Leonard J.
Jerga, Agoston
description Molecular gas works: p‐tert‐Butylcalix[4]arene crystals possess large interstitial cavities when grown by sublimation and, although nonporous, are able to absorb and retain gases such as O2, N2, and CO2 under near‐ambient conditions. H2 is not retained and thus the material can be used to effect the separation of H2 from gas mixtures. The gas can be removed by evacuation or immersion of the crystals in nitrobenzene (see picture).
doi_str_mv 10.1002/anie.200353559
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source Wiley Online Library Journals Frontfile Complete
subjects absorption
calixarenes
host-guest systems
hydrogen
inclusion compounds
title A New Type of Material for the Recovery of Hydrogen from Gas Mixtures
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