Noncovalent Engineering of Carbon Nanotube Surfaces by Rigid, Functional Conjugated Polymers

We report a new nonwrapping approach to noncovalent engineering of carbon nanotube surfaces by short, rigid functional conjugated polymers, poly(aryleneethynylene)s. Our technique not only enables the dissolution of various types of carbon nanotubes in organic solvents, which represents the first ex...

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Veröffentlicht in:Journal of the American Chemical Society 2002-08, Vol.124 (31), p.9034-9035
Hauptverfasser: Chen, Jian, Liu, Haiying, Weimer, Wayne A, Halls, Mathew D, Waldeck, David H, Walker, Gilbert C
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container_end_page 9035
container_issue 31
container_start_page 9034
container_title Journal of the American Chemical Society
container_volume 124
creator Chen, Jian
Liu, Haiying
Weimer, Wayne A
Halls, Mathew D
Waldeck, David H
Walker, Gilbert C
description We report a new nonwrapping approach to noncovalent engineering of carbon nanotube surfaces by short, rigid functional conjugated polymers, poly(aryleneethynylene)s. Our technique not only enables the dissolution of various types of carbon nanotubes in organic solvents, which represents the first example of solubilization of carbon nanotubes via π-stacking without polymer wrapping, but could also introduce numerous neutral and ionic functional groups onto the carbon nanotube surfaces.
doi_str_mv 10.1021/ja026104m
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subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Solution and gel properties
title Noncovalent Engineering of Carbon Nanotube Surfaces by Rigid, Functional Conjugated Polymers
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