MOCVD-Loading of Mesoporous Siliceous Matrices with Cu/ZnO: Supported Catalysts for Methanol Synthesis
Consecutive vaporization cycles for the preparation of heterogeneous catalysts: Active Cu‐ and ZnO‐containing methanol‐synthesis catalysts were obtained by vaporizing suitable organometallic precursors into mesoporous silicates, followed by thermal treatment (see scheme). The catalytically active co...
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Veröffentlicht in: | Angewandte Chemie International Edition 2004-05, Vol.43 (21), p.2839-2842 |
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creator | Becker, Ralf Parala, Harish Hipler, Frank Tkachenko, Olga P. Klementiev, Konstantin V. Grünert, Wolfgang Wilmer, Hagen Hinrichsen, Olaf Muhler, Martin Birkner, Alexander Wöll, Christof Schäfer, Sven Fischer, Roland A. |
description | Consecutive vaporization cycles for the preparation of heterogeneous catalysts: Active Cu‐ and ZnO‐containing methanol‐synthesis catalysts were obtained by vaporizing suitable organometallic precursors into mesoporous silicates, followed by thermal treatment (see scheme). The catalytically active components in the final material have nanoscopic dimensions. The methanol production by the catalysts is similar to that of systems synthesized by the classical route. |
doi_str_mv | 10.1002/anie.200351166 |
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subjects | copper CVD (chemical vapor deposition) heterogeneous catalysis mesoporous materials methanol synthesis zinc oxide |
title | MOCVD-Loading of Mesoporous Siliceous Matrices with Cu/ZnO: Supported Catalysts for Methanol Synthesis |
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