Facile synthesis of 17-formyl steroids via palladium-catalyzed homogeneous carbonylation reaction

17-Formyl-androst-16-ene and its analogues were synthesized from the corresponding 17-iodo-16-ene derivatives in palladium-catalyzed formylation reaction using tributyltin hydride as hydrogen source under mild reaction conditions. The formation of androst-16-ene and its isomerization products, as we...

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Veröffentlicht in:	Steroids 2002-08, Vol.67 (9), p.777-781
Hauptverfasser:	Petz, Andrea, Horváth, Judit, Tuba, Zoltán, Pintér, Zoltán, Kollár, László
Format:	Artikel
Sprache:	eng
Schlagworte:	17-Formyl-steroids 17-Iodo-16-enes Alicyclic compounds, terpenoids, prostaglandins, steroids Carbonylation Catalysis Chemistry Exact sciences and technology Molecular Structure Organic chemistry Palladium - chemistry Palladium catalysts Preparations and properties Steroids Steroids - chemical synthesis Steroids - chemistry Structure-Activity Relationship Tributyltin hydride
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