Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides

Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides

A series of composite lithium- or sodium-magnesium-alkoxide-diisopropylamides of general formula [(MMg[N(Pri)2]2OR)2] (where M = Li, R = Octn; M = Na, R = Bun or Octn), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-06 (11), p.1176-1177
Hauptverfasser: Drewette, Katy J, Henderson, Kenneth W, Kennedy, Alan R, Mulvey, Robert E, O'Hara, Charles T, Rowlings, René B
Format: Artikel
Sprache:eng
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Zusammenfassung:A series of composite lithium- or sodium-magnesium-alkoxide-diisopropylamides of general formula [(MMg[N(Pri)2]2OR)2] (where M = Li, R = Octn; M = Na, R = Bun or Octn), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.
ISSN:1359-7345
1364-548X
DOI:10.1039/b202549c