Steroids and triterpenes from Eleocharis acutangula and E. sellowiana (Cyperaceae)
From the hexane extract of the underground parts of Eleocharis acutangula (Roxb.) Schult., lup-20(29)-ene-3beta,16beta-diol and a mixture of campesterol, stigmasterol and sitosterol were isolated. The hexane extracts of aerial and underground parts of E. sellowiana Kunth furnished two new substances...
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Veröffentlicht in: | Phytochemical analysis 2004-03, Vol.15 (2), p.125-129 |
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creator | Amaral, M. do C.E Faria, A.D Magalhaes, A.F Magalhaes, E.G Ruiz, A.L.T.G |
description | From the hexane extract of the underground parts of Eleocharis acutangula (Roxb.) Schult., lup-20(29)-ene-3beta,16beta-diol and a mixture of campesterol, stigmasterol and sitosterol were isolated. The hexane extracts of aerial and underground parts of E. sellowiana Kunth furnished two new substances, namely neohop-13(18)-en-3alpha-ol and stigmast-22-en-3beta,6beta,9alpha-triol, together with a mixture of steroids, betulinic acid, stigmast-4-en-6beta-ol-3-one and fern-9(11)-en-3alpha-ol. The molecular structures were determined by spectral analysis (1D- and 2D-NMR experiments and MS) and comparison with literature data. |
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Schult., lup-20(29)-ene-3beta,16beta-diol and a mixture of campesterol, stigmasterol and sitosterol were isolated. The hexane extracts of aerial and underground parts of E. sellowiana Kunth furnished two new substances, namely neohop-13(18)-en-3alpha-ol and stigmast-22-en-3beta,6beta,9alpha-triol, together with a mixture of steroids, betulinic acid, stigmast-4-en-6beta-ol-3-one and fern-9(11)-en-3alpha-ol. The molecular structures were determined by spectral analysis (1D- and 2D-NMR experiments and MS) and comparison with literature data.</description><identifier>ISSN: 0958-0344</identifier><identifier>EISSN: 1099-1565</identifier><identifier>DOI: 10.1002/pca.757</identifier><identifier>PMID: 15116945</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>campesterol ; chemical structure ; Cyperaceae ; Cyperaceae - chemistry ; Eleocharis ; Eleocharis - chemistry ; Eleocharis acutangula ; Eleocharis sellowiana ; Freshwater ; Hexanes - analysis ; Molecular Structure ; Nuclear Magnetic Resonance, Biomolecular ; pentacyclic triterpenes ; phytochemicals ; phytosterols ; plant extracts ; sitosterols ; spectral analysis ; steroids ; Steroids - analysis ; Steroids - chemistry ; Steroids - isolation & purification ; stigmasterol ; Structure determination ; Triterpenes - chemistry ; Triterpenes - isolation & purification ; triterpenoids</subject><ispartof>Phytochemical analysis, 2004-03, Vol.15 (2), p.125-129</ispartof><rights>Copyright © 2004 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4067-6cae5db3abe9be62bc80ed88ad2793b66195ac75014d4823f2f2b1c64faed5773</citedby><cites>FETCH-LOGICAL-c4067-6cae5db3abe9be62bc80ed88ad2793b66195ac75014d4823f2f2b1c64faed5773</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpca.757$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpca.757$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/15116945$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Amaral, M. do C.E</creatorcontrib><creatorcontrib>Faria, A.D</creatorcontrib><creatorcontrib>Magalhaes, A.F</creatorcontrib><creatorcontrib>Magalhaes, E.G</creatorcontrib><creatorcontrib>Ruiz, A.L.T.G</creatorcontrib><title>Steroids and triterpenes from Eleocharis acutangula and E. sellowiana (Cyperaceae)</title><title>Phytochemical analysis</title><addtitle>Phytochem. Anal</addtitle><description>From the hexane extract of the underground parts of Eleocharis acutangula (Roxb.) Schult., lup-20(29)-ene-3beta,16beta-diol and a mixture of campesterol, stigmasterol and sitosterol were isolated. The hexane extracts of aerial and underground parts of E. sellowiana Kunth furnished two new substances, namely neohop-13(18)-en-3alpha-ol and stigmast-22-en-3beta,6beta,9alpha-triol, together with a mixture of steroids, betulinic acid, stigmast-4-en-6beta-ol-3-one and fern-9(11)-en-3alpha-ol. The molecular structures were determined by spectral analysis (1D- and 2D-NMR experiments and MS) and comparison with literature data.</description><subject>campesterol</subject><subject>chemical structure</subject><subject>Cyperaceae</subject><subject>Cyperaceae - chemistry</subject><subject>Eleocharis</subject><subject>Eleocharis - chemistry</subject><subject>Eleocharis acutangula</subject><subject>Eleocharis sellowiana</subject><subject>Freshwater</subject><subject>Hexanes - analysis</subject><subject>Molecular Structure</subject><subject>Nuclear Magnetic Resonance, Biomolecular</subject><subject>pentacyclic triterpenes</subject><subject>phytochemicals</subject><subject>phytosterols</subject><subject>plant extracts</subject><subject>sitosterols</subject><subject>spectral analysis</subject><subject>steroids</subject><subject>Steroids - analysis</subject><subject>Steroids - chemistry</subject><subject>Steroids - isolation & purification</subject><subject>stigmasterol</subject><subject>Structure determination</subject><subject>Triterpenes - chemistry</subject><subject>Triterpenes - isolation & purification</subject><subject>triterpenoids</subject><issn>0958-0344</issn><issn>1099-1565</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqF0c1u1DAUBWALgehQEG8AWZUilMF2_LusRsOAVErFtIKddePclEAmCXaiMm9fl4xghVhZ1v10ZJ9LyHNGl4xS_nbwsNRSPyALRq3NmVTyIVlQK01OCyGOyJMYv1OaZlY9JkdMMqaskAvyeTti6JsqZtBV2RiadB2ww5jVod9l6xZ7_w1Ck-Z-GqG7mVr4TdfLLGLb9rcNdJCdrvYDBvAI-PopeVRDG_HZ4Twm1-_WV6v3-fmnzYfV2XnuBVU6Vx5QVmUBJdoSFS-9oVgZAxXXtiiVYlaC15IyUQnDi5rXvGReiRqwkloXx-Rkzh1C_3PCOLpdE316E3TYT9FpZoxm1PwXMs1NwS1N8NUMfehjDFi7ITQ7CHvHqLvv2aWeXeo5yReHyKncYfXXHYpN4M0MbpsW9__KcZerszkun3UTR_z1R0P44ZQutHRfLjZue_Vxe7G5_Oruf_Ry9jX0Dm7Setz1llNWpA1rzoUo7gBtTZ6a</recordid><startdate>200403</startdate><enddate>200403</enddate><creator>Amaral, M. do C.E</creator><creator>Faria, A.D</creator><creator>Magalhaes, A.F</creator><creator>Magalhaes, E.G</creator><creator>Ruiz, A.L.T.G</creator><general>John Wiley & Sons, Ltd</general><scope>FBQ</scope><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>F1W</scope><scope>H95</scope><scope>L.G</scope><scope>7X8</scope></search><sort><creationdate>200403</creationdate><title>Steroids and triterpenes from Eleocharis acutangula and E. sellowiana (Cyperaceae)</title><author>Amaral, M. do C.E ; Faria, A.D ; Magalhaes, A.F ; Magalhaes, E.G ; Ruiz, A.L.T.G</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4067-6cae5db3abe9be62bc80ed88ad2793b66195ac75014d4823f2f2b1c64faed5773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>campesterol</topic><topic>chemical structure</topic><topic>Cyperaceae</topic><topic>Cyperaceae - chemistry</topic><topic>Eleocharis</topic><topic>Eleocharis - chemistry</topic><topic>Eleocharis acutangula</topic><topic>Eleocharis sellowiana</topic><topic>Freshwater</topic><topic>Hexanes - analysis</topic><topic>Molecular Structure</topic><topic>Nuclear Magnetic Resonance, Biomolecular</topic><topic>pentacyclic triterpenes</topic><topic>phytochemicals</topic><topic>phytosterols</topic><topic>plant extracts</topic><topic>sitosterols</topic><topic>spectral analysis</topic><topic>steroids</topic><topic>Steroids - analysis</topic><topic>Steroids - chemistry</topic><topic>Steroids - isolation & purification</topic><topic>stigmasterol</topic><topic>Structure determination</topic><topic>Triterpenes - chemistry</topic><topic>Triterpenes - isolation & purification</topic><topic>triterpenoids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Amaral, M. do C.E</creatorcontrib><creatorcontrib>Faria, A.D</creatorcontrib><creatorcontrib>Magalhaes, A.F</creatorcontrib><creatorcontrib>Magalhaes, E.G</creatorcontrib><creatorcontrib>Ruiz, A.L.T.G</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 1: Biological Sciences & Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>MEDLINE - Academic</collection><jtitle>Phytochemical analysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Amaral, M. do C.E</au><au>Faria, A.D</au><au>Magalhaes, A.F</au><au>Magalhaes, E.G</au><au>Ruiz, A.L.T.G</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Steroids and triterpenes from Eleocharis acutangula and E. sellowiana (Cyperaceae)</atitle><jtitle>Phytochemical analysis</jtitle><addtitle>Phytochem. Anal</addtitle><date>2004-03</date><risdate>2004</risdate><volume>15</volume><issue>2</issue><spage>125</spage><epage>129</epage><pages>125-129</pages><issn>0958-0344</issn><eissn>1099-1565</eissn><abstract>From the hexane extract of the underground parts of Eleocharis acutangula (Roxb.) Schult., lup-20(29)-ene-3beta,16beta-diol and a mixture of campesterol, stigmasterol and sitosterol were isolated. The hexane extracts of aerial and underground parts of E. sellowiana Kunth furnished two new substances, namely neohop-13(18)-en-3alpha-ol and stigmast-22-en-3beta,6beta,9alpha-triol, together with a mixture of steroids, betulinic acid, stigmast-4-en-6beta-ol-3-one and fern-9(11)-en-3alpha-ol. The molecular structures were determined by spectral analysis (1D- and 2D-NMR experiments and MS) and comparison with literature data.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><pmid>15116945</pmid><doi>10.1002/pca.757</doi><tpages>5</tpages></addata></record> |
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subjects | campesterol chemical structure Cyperaceae Cyperaceae - chemistry Eleocharis Eleocharis - chemistry Eleocharis acutangula Eleocharis sellowiana Freshwater Hexanes - analysis Molecular Structure Nuclear Magnetic Resonance, Biomolecular pentacyclic triterpenes phytochemicals phytosterols plant extracts sitosterols spectral analysis steroids Steroids - analysis Steroids - chemistry Steroids - isolation & purification stigmasterol Structure determination Triterpenes - chemistry Triterpenes - isolation & purification triterpenoids |
title | Steroids and triterpenes from Eleocharis acutangula and E. sellowiana (Cyperaceae) |
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