Variations in the Profile and Content of Anthocyanins in Wines Made from Cabernet Sauvignon and Hybrid Grapes

To detect adulteration of wine, it has been proposed that the ratio of acetylated to p-coumaroylated conjugates of nine characteristic anthocyanins can be used to determine whether a wine is derived from Cabernet Sauvignon or hybrid grapes. If the ratio is >3, then a wine is classified as being d...

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Veröffentlicht in:Journal of agricultural and food chemistry 2002-07, Vol.50 (14), p.4096-4102
Hauptverfasser: Burns, Jennifer, Mullen, William, Landrault, Nicholas, Teissedre, Pierre-Louis, Lean, Michael E. J, Crozier, Alan
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container_end_page 4102
container_issue 14
container_start_page 4096
container_title Journal of agricultural and food chemistry
container_volume 50
creator Burns, Jennifer
Mullen, William
Landrault, Nicholas
Teissedre, Pierre-Louis
Lean, Michael E. J
Crozier, Alan
description To detect adulteration of wine, it has been proposed that the ratio of acetylated to p-coumaroylated conjugates of nine characteristic anthocyanins can be used to determine whether a wine is derived from Cabernet Sauvignon or hybrid grapes. If the ratio is >3, then a wine is classified as being derived from Cabernet Sauvignon grapes. This test has significant commercial implications as it is being used to decide whether Cabernet Sauvignon-labeled wines are genuine and can be imported into Germany. To assess whether this is a valid approach, 24 wines were analyzed, 4 of which were made from hybrids and 20 from Cabernet Sauvignon, with vintages ranging from 1993 to 2000. Only 13 of the Cabernet Sauvignon wines contained all nine of the “characteristic” anthocyanins, and the ratio of acetylated to p-coumaroylated derivatives varied from 1.2 to 6.5. It is evident that the use of the anthocyanin ratio method is flawed and that examination of the whole anthocyanin profile and/or investigation of the proportion of monoglucoside and acetylated anthocyanins is a better approach to distinguish between hybrid and Cabernet Sauvignon wines. Keywords: Anthocyanins; red wine; vinification; adulteration
doi_str_mv 10.1021/jf011233s
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subjects Acetylation
Anthocyanins - analysis
Biological and medical sciences
Chromatography, High Pressure Liquid
Chromatography, Liquid
Fermented food industries
Food industries
Fundamental and applied biological sciences. Psychology
Mass Spectrometry
Phenols - analysis
Species Specificity
Vitis - chemistry
Vitis - classification
Wine - analysis
Wine - classification
Wines and vinegars
title Variations in the Profile and Content of Anthocyanins in Wines Made from Cabernet Sauvignon and Hybrid Grapes
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