Cobalt Cluster-Containing Carbonyl Ylides for Catalytic, Three-Component Assembly of Oxygen Heterocycles

A dicobalt hexacarbonyl (Co2(CO)6) cluster is essential for the unusually broad dipolarophile scope and for the sense and degree of diastereoselection in a catalytic, three-component synthesis of tetrahydrofurans and dihydrofurans. Likely involving a new class of carbonyl ylide, these cycloadditions...

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Veröffentlicht in:	Organic letters 2002-06, Vol.4 (13), p.2277-2280
Hauptverfasser:	Skaggs, Aaron J, Lin, Eleanor Y, Jamison, Timothy F
Format:	Artikel
Sprache:	eng
Schlagworte:	Biological Factors - chemical synthesis Catalysis Cobalt - chemistry Furans - chemical synthesis Heterocyclic Compounds - chemical synthesis Molecular Structure Organometallic Compounds - chemistry Oxygen - chemistry Stereoisomerism
Online-Zugang:	Volltext
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