Metal ion scrambling in hexanuclear M(6)(Et(2)NCO(2))(12) complexes (M = Co, Mg). Synthesis, solid state structure, and solution dynamics of heteronuclear Co(n)Mg(6-n)(Et(2)NCO(2))(12) complexes

Heteronuclear diethylcarbamato complexes of the form Co(n)()Mg(6)(-)(n)()(Et(2)NCO(2))(12) were prepared from the isostructural homonuclear precursors Mg(6)(Et(2)NCO(2))(12), 1, and Co(6)(Et(2)NCO(2))(12), 2, via a solvothermal methodology. Two materials were selected for single-crystal X-ray diffra...

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Veröffentlicht in:	Inorganic chemistry 2002-06, Vol.41 (12), p.3183-3190
Hauptverfasser:	Caudle, M Tyler, Benedict, Jason B, Mobley, Charles K, Straessler, Nicholas A, Groy, Thomas L
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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