Syntheses and Spectroscopic and Quadratic Nonlinear Optical Properties of Extended Dipolar Complexes with Ruthenium(II) Ammine Electron Donor and N-Methylpyridinium Acceptor Groups

In this paper, we describe the extremely unusual optical properties of RuII-based electron donor−acceptor (D−A) polyene and some closely related chromophores. For three different polyene series, the intense, visible d→π* metal-to-ligand charge-transfer bands unexpectedly blue-shift as the number of...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 2004-03, Vol.126 (12), p.3880-3891
Hauptverfasser:	Coe, Benjamin J, Jones, Lathe A, Harris, James A, Brunschwig, Bruce S, Asselberghs, Inge, Clays, Koen, Persoons, André, Garín, Javier, Orduna, Jesús
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Preparations and properties
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!