Electronic Effects and the Stereochemistries in Rearrangement−Displacement Reactions of Triaryl(halomethyl)silanes with Fluoride and with Alkoxide Ions

Tetrabutylammonium fluoride (TBAF) reacts with (halomethyl)diphenyl(para-substituted-phenyl)silanes (13, X = Cl), 14 (X = Br), and 15 (X = I) in ether solvents to give fluorodiphenyl(para-substituted-phenylmethyl)silanes (17a) and fluorophenyl(phenylmethyl)(para-substituted-phenyl)silanes (20a) by a...

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Veröffentlicht in:	Journal of organic chemistry 2002-05, Vol.67 (11), p.3561-3574
Hauptverfasser:	Allen, John M, Aprahamian, Steve L, Sans, Esther A, Shechter, Harold
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Organic chemistry Organometalloidal and organometallic compounds Preparations and properties Si derivatives
Online-Zugang:	Volltext
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