Rh(I)-Catalyzed Intramolecular Allenic Pauson−Khand Reaction:  Construction of a Bicyclo[5.3.0]dec-1,7-dien-9-one Skeleton

Rh(I)-Catalyzed Intramolecular Allenic Pauson−Khand Reaction:  Construction of a Bicyclo[5.3.0]dec-1,7-dien-9-one Skeleton

1-Phenylsulfonylallenes possessing a hexynyl appendage in refluxing toluene in the presence of catalytic amount of rhodium(I) catalyst under a carbon monoxide atmosphere underwent regioselective formal [2 + 2 + 1]-cycloaddition to produce the corresponding bicyclo[5.3.0]dec-1,7-dien-9-one derivative...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2002-05, Vol.4 (10), p.1755-1758
Hauptverfasser: Mukai, Chisato, Nomura, Izumi, Yamanishi, Kei, Hanaoka, Miyoji
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 1758
container_issue 10
container_start_page 1755
container_title Organic letters
container_volume 4
creator Mukai, Chisato
Nomura, Izumi
Yamanishi, Kei
Hanaoka, Miyoji
description 1-Phenylsulfonylallenes possessing a hexynyl appendage in refluxing toluene in the presence of catalytic amount of rhodium(I) catalyst under a carbon monoxide atmosphere underwent regioselective formal [2 + 2 + 1]-cycloaddition to produce the corresponding bicyclo[5.3.0]dec-1,7-dien-9-one derivatives in acceptable yields.
doi_str_mv 10.1021/ol020051w
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_71701811</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>71701811</sourcerecordid><originalsourceid>FETCH-LOGICAL-a377t-c962fde53950aaeb25b12b849afa6299d864c518016d34568e6a10f3bd7ef0bb3</originalsourceid><addsrcrecordid>eNpt0E1rFEEQBuAmKObz4B-QvigJ2Juunu358BYXo4uBhCSeRIaa7hoysbc7ds8g60FyTK7-xPwSR3eJF09VFA8v1MvYc5ATkAoOg5NKSg3fN9gWaJWJQmr15HHP5SbbTulaShgv1TO2CSOXqoIt9vP8an9-IGbYo1v-IMvnvo-4CI7M4DDyI-fId4af4ZCCf7j79fEKveXnhKbvgn_zcHvPZ8GnPg5_Dzy0HPnbziyNC5_1JJvIL5aMgNeFsB15UYngiV98JUd98LvsaYsu0d567rBPx-8uZx_Eyen7-ezoRGBWFL0wVa5aSzqrtESkRukGVFNOK2wxV1Vly3xqNJQScptNdV5SjiDbrLEFtbJpsh32apV7E8O3gVJfL7pkyDn0FIZUF1BIKAFGeLCCJoaUIrX1TewWGJc1yPpP2fVj2aN9sQ4dmgXZf3Ld7ghergCaVF-HIfrxx_8E_QasfIa6</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>71701811</pqid></control><display><type>article</type><title>Rh(I)-Catalyzed Intramolecular Allenic Pauson−Khand Reaction:  Construction of a Bicyclo[5.3.0]dec-1,7-dien-9-one Skeleton</title><source>American Chemical Society</source><creator>Mukai, Chisato ; Nomura, Izumi ; Yamanishi, Kei ; Hanaoka, Miyoji</creator><creatorcontrib>Mukai, Chisato ; Nomura, Izumi ; Yamanishi, Kei ; Hanaoka, Miyoji</creatorcontrib><description>1-Phenylsulfonylallenes possessing a hexynyl appendage in refluxing toluene in the presence of catalytic amount of rhodium(I) catalyst under a carbon monoxide atmosphere underwent regioselective formal [2 + 2 + 1]-cycloaddition to produce the corresponding bicyclo[5.3.0]dec-1,7-dien-9-one derivatives in acceptable yields.</description><identifier>ISSN: 1523-7060</identifier><identifier>EISSN: 1523-7052</identifier><identifier>DOI: 10.1021/ol020051w</identifier><identifier>PMID: 12000291</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Organic letters, 2002-05, Vol.4 (10), p.1755-1758</ispartof><rights>Copyright © 2002 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a377t-c962fde53950aaeb25b12b849afa6299d864c518016d34568e6a10f3bd7ef0bb3</citedby><cites>FETCH-LOGICAL-a377t-c962fde53950aaeb25b12b849afa6299d864c518016d34568e6a10f3bd7ef0bb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ol020051w$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ol020051w$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>315,781,785,2766,27080,27928,27929,56742,56792</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/12000291$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Mukai, Chisato</creatorcontrib><creatorcontrib>Nomura, Izumi</creatorcontrib><creatorcontrib>Yamanishi, Kei</creatorcontrib><creatorcontrib>Hanaoka, Miyoji</creatorcontrib><title>Rh(I)-Catalyzed Intramolecular Allenic Pauson−Khand Reaction:  Construction of a Bicyclo[5.3.0]dec-1,7-dien-9-one Skeleton</title><title>Organic letters</title><addtitle>Org. Lett</addtitle><description>1-Phenylsulfonylallenes possessing a hexynyl appendage in refluxing toluene in the presence of catalytic amount of rhodium(I) catalyst under a carbon monoxide atmosphere underwent regioselective formal [2 + 2 + 1]-cycloaddition to produce the corresponding bicyclo[5.3.0]dec-1,7-dien-9-one derivatives in acceptable yields.</description><issn>1523-7060</issn><issn>1523-7052</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNpt0E1rFEEQBuAmKObz4B-QvigJ2Juunu358BYXo4uBhCSeRIaa7hoysbc7ds8g60FyTK7-xPwSR3eJF09VFA8v1MvYc5ATkAoOg5NKSg3fN9gWaJWJQmr15HHP5SbbTulaShgv1TO2CSOXqoIt9vP8an9-IGbYo1v-IMvnvo-4CI7M4DDyI-fId4af4ZCCf7j79fEKveXnhKbvgn_zcHvPZ8GnPg5_Dzy0HPnbziyNC5_1JJvIL5aMgNeFsB15UYngiV98JUd98LvsaYsu0d567rBPx-8uZx_Eyen7-ezoRGBWFL0wVa5aSzqrtESkRukGVFNOK2wxV1Vly3xqNJQScptNdV5SjiDbrLEFtbJpsh32apV7E8O3gVJfL7pkyDn0FIZUF1BIKAFGeLCCJoaUIrX1TewWGJc1yPpP2fVj2aN9sQ4dmgXZf3Ld7ghergCaVF-HIfrxx_8E_QasfIa6</recordid><startdate>20020516</startdate><enddate>20020516</enddate><creator>Mukai, Chisato</creator><creator>Nomura, Izumi</creator><creator>Yamanishi, Kei</creator><creator>Hanaoka, Miyoji</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20020516</creationdate><title>Rh(I)-Catalyzed Intramolecular Allenic Pauson−Khand Reaction:  Construction of a Bicyclo[5.3.0]dec-1,7-dien-9-one Skeleton</title><author>Mukai, Chisato ; Nomura, Izumi ; Yamanishi, Kei ; Hanaoka, Miyoji</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a377t-c962fde53950aaeb25b12b849afa6299d864c518016d34568e6a10f3bd7ef0bb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mukai, Chisato</creatorcontrib><creatorcontrib>Nomura, Izumi</creatorcontrib><creatorcontrib>Yamanishi, Kei</creatorcontrib><creatorcontrib>Hanaoka, Miyoji</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Organic letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mukai, Chisato</au><au>Nomura, Izumi</au><au>Yamanishi, Kei</au><au>Hanaoka, Miyoji</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rh(I)-Catalyzed Intramolecular Allenic Pauson−Khand Reaction:  Construction of a Bicyclo[5.3.0]dec-1,7-dien-9-one Skeleton</atitle><jtitle>Organic letters</jtitle><addtitle>Org. Lett</addtitle><date>2002-05-16</date><risdate>2002</risdate><volume>4</volume><issue>10</issue><spage>1755</spage><epage>1758</epage><pages>1755-1758</pages><issn>1523-7060</issn><eissn>1523-7052</eissn><abstract>1-Phenylsulfonylallenes possessing a hexynyl appendage in refluxing toluene in the presence of catalytic amount of rhodium(I) catalyst under a carbon monoxide atmosphere underwent regioselective formal [2 + 2 + 1]-cycloaddition to produce the corresponding bicyclo[5.3.0]dec-1,7-dien-9-one derivatives in acceptable yields.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>12000291</pmid><doi>10.1021/ol020051w</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1523-7060
ispartof Organic letters, 2002-05, Vol.4 (10), p.1755-1758
issn 1523-7060
1523-7052
language eng
recordid cdi_proquest_miscellaneous_71701811
source American Chemical Society
title Rh(I)-Catalyzed Intramolecular Allenic Pauson−Khand Reaction:  Construction of a Bicyclo[5.3.0]dec-1,7-dien-9-one Skeleton
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-16T21%3A53%3A38IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Rh(I)-Catalyzed%20Intramolecular%20Allenic%20Pauson%E2%88%92Khand%20Reaction:%E2%80%89%20Construction%20of%20a%20Bicyclo%5B5.3.0%5Ddec-1,7-dien-9-one%20Skeleton&rft.jtitle=Organic%20letters&rft.au=Mukai,%20Chisato&rft.date=2002-05-16&rft.volume=4&rft.issue=10&rft.spage=1755&rft.epage=1758&rft.pages=1755-1758&rft.issn=1523-7060&rft.eissn=1523-7052&rft_id=info:doi/10.1021/ol020051w&rft_dat=%3Cproquest_cross%3E71701811%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=71701811&rft_id=info:pmid/12000291&rfr_iscdi=true