Assembling Process of Charged Nonanuclear Cationic Lanthanide(III) Clusters Assisted by Dichromium Decacarbonyl Hydride

The reaction of Ln(acac)3·3H2O (Ln = Sm, Eu, Gd, Dy, Yb) with K[Cr2(CO)10(μ-H)] at different molar ratios and solvents leads to the formation of nonanuclear lanthanide hydroxo acetylacetonate complexes of general formula [Ln9(OH)10(acac)16][HCr2(CO)10]. The compounds are isomorphous, and the common...

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Veröffentlicht in:	Inorganic chemistry 2004-03, Vol.43 (5), p.1603-1605
Hauptverfasser:	Addamo, Maurizio, Bombieri, Gabriella, Foresti, Elisabetta, Grillone, M. Domenica, Volpe, Maurizio
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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