Tuning the Architecture of Mesostructures by Electrodeposition

When the dimension of materials decreases to mesoscale, their properties can change dramatically, depending on the boundary conditions imposed by the sample architecture including geometry, morphology, and hierarchical structures. Here we show that electrodeposition, a method for reducing materials...

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Veröffentlicht in:Journal of the American Chemical Society 2004-03, Vol.126 (8), p.2316-2317
Hauptverfasser: Xiao, Zhi-Li, Han, Catherine Y, Kwok, Wai-Kwong, Wang, Hsien-Hau, Welp, Ulrich, Wang, Jian, Crabtree, George W
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container_end_page 2317
container_issue 8
container_start_page 2316
container_title Journal of the American Chemical Society
container_volume 126
creator Xiao, Zhi-Li
Han, Catherine Y
Kwok, Wai-Kwong
Wang, Hsien-Hau
Welp, Ulrich
Wang, Jian
Crabtree, George W
description When the dimension of materials decreases to mesoscale, their properties can change dramatically, depending on the boundary conditions imposed by the sample architecture including geometry, morphology, and hierarchical structures. Here we show that electrodeposition, a method for reducing materials from a solution onto a substrate, can provide a versatile pathway to tailor the architecture of mesostructures. Novel lead (Pb) structures ranging from nanowires, mesoparticles with octahedral, decahedral, and icosahedral shapes to porous nanowires, multipods, nanobrushes, and even snowflake-shaped structures were synthesized through systematically exploring electrodeposition parameters including reduction potentials, solution concentration, starting materials, supporting electrolytes, and surfactants.
doi_str_mv 10.1021/ja0315154
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subjects Cross-disciplinary physics: materials science
rheology
Electrodeposition, electroplating
Exact sciences and technology
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Physics
title Tuning the Architecture of Mesostructures by Electrodeposition
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