Tuning the Architecture of Mesostructures by Electrodeposition
When the dimension of materials decreases to mesoscale, their properties can change dramatically, depending on the boundary conditions imposed by the sample architecture including geometry, morphology, and hierarchical structures. Here we show that electrodeposition, a method for reducing materials...
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Veröffentlicht in: | Journal of the American Chemical Society 2004-03, Vol.126 (8), p.2316-2317 |
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container_title | Journal of the American Chemical Society |
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creator | Xiao, Zhi-Li Han, Catherine Y Kwok, Wai-Kwong Wang, Hsien-Hau Welp, Ulrich Wang, Jian Crabtree, George W |
description | When the dimension of materials decreases to mesoscale, their properties can change dramatically, depending on the boundary conditions imposed by the sample architecture including geometry, morphology, and hierarchical structures. Here we show that electrodeposition, a method for reducing materials from a solution onto a substrate, can provide a versatile pathway to tailor the architecture of mesostructures. Novel lead (Pb) structures ranging from nanowires, mesoparticles with octahedral, decahedral, and icosahedral shapes to porous nanowires, multipods, nanobrushes, and even snowflake-shaped structures were synthesized through systematically exploring electrodeposition parameters including reduction potentials, solution concentration, starting materials, supporting electrolytes, and surfactants. |
doi_str_mv | 10.1021/ja0315154 |
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subjects | Cross-disciplinary physics: materials science rheology Electrodeposition, electroplating Exact sciences and technology Materials science Methods of deposition of films and coatings film growth and epitaxy Physics |
title | Tuning the Architecture of Mesostructures by Electrodeposition |
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