Synthesis and Solid-State Structure of Perfluorophenyl End-Capped Polyynes

Synthesis and Solid-State Structure of Perfluorophenyl End-Capped Polyynes

Five new supramolecular building blocks have been synthesized on the basis of polyynes end-capped with pentafluorophenyl groups, including three symmetrical (16, 17, 18) and two unsymmetrical polyynes (7 and 12). The solid-state behavior of these molecules based on the attractive electrostatic inter...

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Veröffentlicht in:Organic letters 2008-06, Vol.10 (11), p.2163-2166
Hauptverfasser: Kendall, Jamie, McDonald, Robert, Ferguson, Michael J, Tykwinski, Rik R
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container_title Organic letters
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creator Kendall, Jamie
McDonald, Robert
Ferguson, Michael J
Tykwinski, Rik R
description Five new supramolecular building blocks have been synthesized on the basis of polyynes end-capped with pentafluorophenyl groups, including three symmetrical (16, 17, 18) and two unsymmetrical polyynes (7 and 12). The solid-state behavior of these molecules based on the attractive electrostatic interactions of the phenyl and perfluorophenyl groups has been examined by X-ray crystallographic analysis of 7, 12, and 16·25.
doi_str_mv 10.1021/ol800583r
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title Synthesis and Solid-State Structure of Perfluorophenyl End-Capped Polyynes
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