A Highly Active Zinc Catalyst for the Controlled Polymerization of Lactide

We report the preparation, structural characterization, and detailed lactide polymerization behavior of a new Zn(II) alkoxide complex, (L1ZnOEt)2 (L1 = 2,4-di-tert-butyl-6-{[(2‘-dimethylaminoethyl)methylamino]methyl}phenolate). While an X-ray crystal structure revealed the complex to be dimeric in t...

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Veröffentlicht in:	Journal of the American Chemical Society 2003-09, Vol.125 (37), p.11350-11359
Hauptverfasser:	Williams, Charlotte K, Breyfogle, Laurie E, Choi, Sun Kyung, Nam, Wonwoo, Young, Victor G, Hillmyer, Marc A, Tolman, William B
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymers with particular structures Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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