A New Reaction of Aryl Aldehydes with Aryl Acetylenes in the Presence of Boron Trihalides
The reactions of aryl aldehydes with 2 equiv of arylacetylenes in the presence of boron trichloride yield (E,Z)-1,3,5-triaryl-1,5-dichloro-1,4-pentadienes. Reactions carried out in the presence of boron tribromide generate the corresponding (Z,Z)-1,3,5-triaryl-1,5-dibromo-1,4-pentadienes.
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| Veröffentlicht in: | Organic letters 2002-05, Vol.4 (9), p.1491-1493 |
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| container_title | Organic letters |
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| creator | Kabalka, George W Wu, Zhongzhi Ju, Yuhong |
| description | The reactions of aryl aldehydes with 2 equiv of arylacetylenes in the presence of boron trichloride yield (E,Z)-1,3,5-triaryl-1,5-dichloro-1,4-pentadienes. Reactions carried out in the presence of boron tribromide generate the corresponding (Z,Z)-1,3,5-triaryl-1,5-dibromo-1,4-pentadienes. |
| doi_str_mv | 10.1021/ol025696a |
| format | Article |
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| ispartof | Organic letters, 2002-05, Vol.4 (9), p.1491-1493 |
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| language | eng |
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| source | ACS Publications |
| title | A New Reaction of Aryl Aldehydes with Aryl Acetylenes in the Presence of Boron Trihalides |
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