Mechanisms of Hydrogen-, Oxygen-, and Electron-Transfer Reactions of Cumylperoxyl Radical

Rates of hydrogen-transfer reactions from a series of para-substituted N,N-dimethylanilines to cumylperoxyl radical and oxygen-transfer reactions from cumylperoxyl radical to a series of sulfides and phosphines have been determined in propionitrile (EtCN) and pentane at low temperatures by use of ES...

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Veröffentlicht in:	Journal of the American Chemical Society 2003-07, Vol.125 (30), p.9074-9082
Hauptverfasser:	Fukuzumi, Shunichi, Shimoosako, Kanji, Suenobu, Tomoyoshi, Watanabe, Yoshihito
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Free radicals chemistry Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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