Fate and Kinetic Modeling of Reactivity of Alkanesulfenic Acids and Thiosulfinates in Model Systems and Onion Homogenates

The dynamic changes in thiosulfinate profiles were studied in reaction systems containing a crude onion alliinase, S-alk(en)yl-l-cysteine sulfoxide substrates (1) and preformed thiosulfinates (4). Regioisomeric excesses of one of two possible heterologous 4 species (RS(O)SR‘, where R ≠ R‘) could be...

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Veröffentlicht in:	Journal of agricultural and food chemistry 2002-04, Vol.50 (9), p.2652-2659
Hauptverfasser:	Shen, Cunxi, Hong, Zongxuan, Parkin, Kirk L
Format:	Artikel
Sprache:	eng
Schlagworte:	Agronomy. Soil science and plant productions Alkanes - chemistry Alkanes - metabolism Allium - chemistry Biological and medical sciences Carbon-Sulfur Lyases - metabolism Economic plant physiology Fundamental and applied biological sciences. Psychology General pharmacology Kinetics Medical sciences Models, Chemical Nitrogen metabolism and other ones (excepting carbon metabolism) Nutrition. Photosynthesis. Respiration. Metabolism Pharmacognosy. Homeopathy. Health food Pharmacology. Drug treatments Sulfenic Acids - chemistry Sulfenic Acids - metabolism Sulfinic Acids - chemistry Sulfinic Acids - metabolism
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