Configurationally homogeneous diastereomers of a linear hexa(tertiary phosphine): enantioselective self-assembly of a double-stranded parallel helicate of the type (P)-[Cu(3)(hexaphos)(2)](PF(6))(3)

Three configurationally homogeneous diastereomers of the linear hexa(tertiary phosphine) Ph(2)PCH(2)CH(2)P(Ph)CH(2)CH(2)P(Ph)CH(2)CH(2)P(Ph)CH(2)CH(2)P(Ph)CH(2)CH(2)PPh(2) (hexaphos) have been isolated in enantiomerically pure form, namely (R,S,S,R)-, (R,S,S,S)-, and (S,S,S,S)-hexaphos. The strongly...

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Veröffentlicht in:	Proceedings of the National Academy of Sciences - PNAS 2002-04, Vol.99 (8), p.4877-4882
Hauptverfasser:	Bowyer, Paul K, Cook, Vernon C, Gharib-Naseri, Nahid, Gugger, Paul A, Rae, A David, Swiegers, Gerhard F, Willis, Anthony C, Zank, Johann, Wild, S Bruce
Format:	Artikel
Sprache:	eng
Schlagworte:	Cations Chemistry Chromatography, High Pressure Liquid Crystallography, X-Ray Ligands Macromolecular Substances Magnetic Resonance Spectroscopy Models, Chemical Models, Molecular Phosphines - chemistry Protein Conformation Stereoisomerism Time Factors
Online-Zugang:	Volltext
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