The use of size distributions of circular domains in Langmuir monolayers for determining physical parameters of surfactants

An analysis of equilibrium size distributions of circular liquid-condensed (LC) domains in amphiphilic monolayers at the air/water interface, gleaned from microscopic images, is presented in terms of Gaussians fitted to a theoretical expression derived previously. It is demonstrated how, in principl...

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Veröffentlicht in:Journal of colloid and interface science 2003-08, Vol.264 (2), p.558-560
1. Verfasser: Mulder, Willem H
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description An analysis of equilibrium size distributions of circular liquid-condensed (LC) domains in amphiphilic monolayers at the air/water interface, gleaned from microscopic images, is presented in terms of Gaussians fitted to a theoretical expression derived previously. It is demonstrated how, in principle, important properties of the monolayer, such as molecular dipole moments of surfactant head groups and line tension of the liquid-condensed/liquid-expanded phase boundary, can be obtained by combining the results of this simplified analysis with information from X-ray diffraction or surface pressure measurements.
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subjects Amphiphiles
Brewster angle microscopy
Chemistry
Dipole moments
Exact sciences and technology
Gas-liquid interface and liquid-liquid interface
General and physical chemistry
Line tension
Liquid-condensed domains
Monolayers
Size distributions
Surface physical chemistry
title The use of size distributions of circular domains in Langmuir monolayers for determining physical parameters of surfactants
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