Tetrakis­[1-(3-chloro­propyl)-1,2,4-tri­azole-κN4]­bis­(tetrafluoroborato-κF)copper(II)

Tetrakis­[1-(3-chloro­propyl)-1,2,4-tri­azole-κN4]­bis­(tetrafluoroborato-κF)copper(II)

In the title complex, [Cu(BF4)2(1tpc)4] [1tpc is 1‐(3‐chloro­propyl)‐1,2,4‐triazole, C5H8ClN3], the copper(II) centres reside in a tetragonally distorted octahedral coordination environment. Four 1tpc ligands are coordinated to the metal atom via the N4 atom of the triazole rings in a square‐planar...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2002-04, Vol.58 (4), p.m243-m245
Hauptverfasser: Mills, Allison M., Flinzner, Kristel, Stassen, Arno F., Haasnoot, Jaap G., Spek, Anthony L.
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Metal complexes
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Beschreibung
Zusammenfassung:In the title complex, [Cu(BF4)2(1tpc)4] [1tpc is 1‐(3‐chloro­propyl)‐1,2,4‐triazole, C5H8ClN3], the copper(II) centres reside in a tetragonally distorted octahedral coordination environment. Four 1tpc ligands are coordinated to the metal atom via the N4 atom of the triazole rings in a square‐planar arrangement, with Cu—N bond lengths in the range 2.002 (2)–2.019 (2) Å. Two tetra­fluoro­borate anions, in the axial positions above and below the square plane, are weakly coordinated to the copper(II) centre, with Cu—F distances of 2.4009 (18) and 2.5096 (18) Å.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270102003086