Bonding and Redox Properties of [Os3(CO)9(tmbp)(L)] (tmbp=4,4′,5,5′-tetramethyl-2,2′-biphosphinine; L=CO, PPh3) Clusters with an Unprecedented Electron-Deficient Metallic Core and Doubly Bridging Biphosphinine Dianion

Herein we describe in detail the bonding properties and electrochemical behavior of the first known triosmium carbonyl clusters with a coordinated redox‐active ligand 4,4′,5,5′‐tetramethyl‐2,2′‐biphosphinine (tmbp), the phosphorus derivative of 2,2′‐bipyridine. The clusters investigated were [Os3(CO...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry : a European journal 2002-04, Vol.8 (7), p.1741-1752
Hauptverfasser:	Bakker, Maarten J., Vergeer, Frank W., Hartl, František, Rosa, Patrick, Ricard, Louis, Le Floch, Pascal, Calhorda, Maria J.
Format:	Artikel
Sprache:	eng
Schlagworte:	cluster compounds density functional calculations osmium P ligands spectroelectrochemistry X-ray diffraction
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!