π-Complexation of Biphenyl, Naphthalene, and Triphenylene to Trimeric Perfluoro-ortho-phenylene Mercury. Formation of Extended Binary Stacks with Unusual Luminescent Properties

Trimeric perfluoro-ortho-phenylene mercury (1) crystallizes from CS2 as a pure compound. In the crystal, 1 forms staggered cofacial dimers (centroid distance of 3.38 Å). In the dimer, the indivdual components are associated via long mercury−π interactions (3.443 < Hg···C < 3.650 Å). Interestin...

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Veröffentlicht in:	Journal of the American Chemical Society 2002-04, Vol.124 (14), p.3737-3742
Hauptverfasser:	Haneline, Mason R, Tsunoda, Mitsukimi, Gabbaï, François P
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic chemistry Organic compounds Organometalloidal and organometallic compounds Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids Transition metals derivatives
Online-Zugang:	Volltext
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