Allylic Phosphates and Allylic Phosphinates as Electrophiles in Efficient Silylcupration Reactions of Acetylenes

Atom-efficient stoichiometric silylcupration reactions of acetylenes followed by electrophilic trapping of the intermediate vinylcopper species with allylic phosphates have been developed. The reaction sequence was also carried out with the use of a catalytic amount of CuCN employing of both allylic...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of organic chemistry 2002-04, Vol.67 (7), p.2136-2143
Hauptverfasser:	Liepins, Vilnis, Karlström, A. Sofia E, Bäckvall, Jan-E
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Organic chemistry Organometalloidal and organometallic compounds Preparations and properties Si derivatives
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!