Electron Spin Catalysis

Electron Spin Catalysis

As a model for testing three spin dynamics Buchachenko and Berdinsky consider a radical triad (R1, R2, R3) in which one of the radicals, R3, is supposed to be a spin catalyst, two others, R1 and R2, are treated as a radical pair born initially in the triplet spin state. The most chemically important...

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Veröffentlicht in:Chemical reviews 2002-03, Vol.102 (3), p.603-612
Hauptverfasser: Buchachenko, Anatoly L, Berdinsky, Vitaly L
Format: Artikel
Sprache:eng
Schlagworte:
Catalysts
Chemical reactions
Electrons
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Zusammenfassung:As a model for testing three spin dynamics Buchachenko and Berdinsky consider a radical triad (R1, R2, R3) in which one of the radicals, R3, is supposed to be a spin catalyst, two others, R1 and R2, are treated as a radical pair born initially in the triplet spin state. The most chemically important result of the nuclear spin selection is the magnetic isotope effect, which fractionates magnetic an nonmagnetic isotopes.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr010370l