Singlet Diradicals: From Transition States to Crystalline Compounds

Singlet diradicals are usually not energy minima. As observed by femtosecond spectroscopy, they readily couple to form σ bonds. Substituent effects allow lifetimes to increase into the microsecond range. Taking advantage of the properties of hetero-elements, a diradical has been prepared that is ind...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2002-03, Vol.295 (5561), p.1880-1881
Hauptverfasser:	Scheschkewitz, David, Amii, Hideki, Gornitzka, Heinz, Schoeller, Wolfgang W., Bourissou, Didier, Bertrand, Guy
Format:	Artikel
Sprache:	eng
Schlagworte:	Atoms Chemical bonding Chemistry Climate Crystallization Electrically conductive materials Electrons Molecules Orbitals Organic Chemistry Radicals (Chemistry) Room temperature Structural Analysis (Linguistics) Structural Analysis (Science)
Online-Zugang:	Volltext
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