Catalytic Dealkylation of Phosphates with Binuclear Boron Compounds
The Salen(tBu) ligand and its derivatives were used to prepare binuclear boron complexes. These compounds have the formula, L(BBr2)2 (L = Salpen(tBu) and Salben(tBu)). These are formed from the reaction of the corresponding L[B(OMe)2]2 with BBr3. They represent a new type of binuclear boron compound...
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| Veröffentlicht in: | Journal of the American Chemical Society 2002-03, Vol.124 (9), p.1864-1865 |
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| container_end_page | 1865 |
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| container_issue | 9 |
| container_start_page | 1864 |
| container_title | Journal of the American Chemical Society |
| container_volume | 124 |
| creator | Keizer, Timothy S De Pue, Lauren J Parkin, Sean Atwood, David A |
| description | The Salen(tBu) ligand and its derivatives were used to prepare binuclear boron complexes. These compounds have the formula, L(BBr2)2 (L = Salpen(tBu) and Salben(tBu)). These are formed from the reaction of the corresponding L[B(OMe)2]2 with BBr3. They represent a new type of binuclear boron compound. These compounds are active towards the dealkylation of many phosphates. They are also catalytically active with a stoichiometric amount of BBr3 to trimethylphosphate. |
| doi_str_mv | 10.1021/ja017360m |
| format | Article |
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These compounds have the formula, L(BBr2)2 (L = Salpen(tBu) and Salben(tBu)). These are formed from the reaction of the corresponding L[B(OMe)2]2 with BBr3. They represent a new type of binuclear boron compound. These compounds are active towards the dealkylation of many phosphates. 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Am. Chem. Soc</addtitle><description>The Salen(tBu) ligand and its derivatives were used to prepare binuclear boron complexes. These compounds have the formula, L(BBr2)2 (L = Salpen(tBu) and Salben(tBu)). These are formed from the reaction of the corresponding L[B(OMe)2]2 with BBr3. They represent a new type of binuclear boron compound. These compounds are active towards the dealkylation of many phosphates. They are also catalytically active with a stoichiometric amount of BBr3 to trimethylphosphate.</description><subject>Alkylation</subject><subject>B derivatives</subject><subject>Boron Compounds - chemistry</subject><subject>Bromides - chemistry</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Molecular Structure</subject><subject>Organic chemistry</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Organophosphates - chemistry</subject><subject>Preparations and properties</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpt0FtLwzAYBuAgipuHC_-A9EbBi2qSNoddunqEiYqH2_A1TVm3tplJi-7fm7HhbrwKH3l4eXkROiH4kmBKrmaAiUg4bnbQkDCKY0Yo30VDjDGNheTJAB14PwtnSiXZRwNCJOdslA5RlkEH9bKrdHRjoJ4va-gq20a2jF6m1i-m0BkffVfdNBpXba9rAy4aWxdIZpuF7dvCH6G9EmpvjjfvIfq4u33PHuLJ8_1jdj2JIRGjLs4LGCWk0KGDpMBwLjglhidFITXRnFCai5TnnJm8kBCqs5HOUyx0KmjJGE8O0fk6d-HsV298p5rKa1PX0BrbeyVIKkUiWIAXa6id9d6ZUi1c1YBbKoLVajH1t1iwp5vQPm9MsZWbiQI42wDwGurSQasrv3UJS0UqcHDx2lW-Mz9__-Dmiq9aqfeXNyWfJq_yLhyf21zQXs1s79qw3T8FfwHah40Z</recordid><startdate>20020306</startdate><enddate>20020306</enddate><creator>Keizer, Timothy S</creator><creator>De Pue, Lauren J</creator><creator>Parkin, Sean</creator><creator>Atwood, David A</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20020306</creationdate><title>Catalytic Dealkylation of Phosphates with Binuclear Boron Compounds</title><author>Keizer, Timothy S ; De Pue, Lauren J ; Parkin, Sean ; Atwood, David A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a379t-bda931dc42882a50b7621e63dd8c1c6122b746b65ebd8a00259cb407c472f5563</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Alkylation</topic><topic>B derivatives</topic><topic>Boron Compounds - chemistry</topic><topic>Bromides - chemistry</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Molecular Structure</topic><topic>Organic chemistry</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Organophosphates - chemistry</topic><topic>Preparations and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Keizer, Timothy S</creatorcontrib><creatorcontrib>De Pue, Lauren J</creatorcontrib><creatorcontrib>Parkin, Sean</creatorcontrib><creatorcontrib>Atwood, David A</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Keizer, Timothy S</au><au>De Pue, Lauren J</au><au>Parkin, Sean</au><au>Atwood, David A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic Dealkylation of Phosphates with Binuclear Boron Compounds</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2002-03-06</date><risdate>2002</risdate><volume>124</volume><issue>9</issue><spage>1864</spage><epage>1865</epage><pages>1864-1865</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>The Salen(tBu) ligand and its derivatives were used to prepare binuclear boron complexes. These compounds have the formula, L(BBr2)2 (L = Salpen(tBu) and Salben(tBu)). These are formed from the reaction of the corresponding L[B(OMe)2]2 with BBr3. They represent a new type of binuclear boron compound. These compounds are active towards the dealkylation of many phosphates. They are also catalytically active with a stoichiometric amount of BBr3 to trimethylphosphate.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>11866594</pmid><doi>10.1021/ja017360m</doi><tpages>2</tpages></addata></record> |
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| ispartof | Journal of the American Chemical Society, 2002-03, Vol.124 (9), p.1864-1865 |
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| source | MEDLINE; ACS Publications |
| subjects | Alkylation B derivatives Boron Compounds - chemistry Bromides - chemistry Catalysis Chemistry Exact sciences and technology Molecular Structure Organic chemistry Organometalloidal and organometallic compounds Organophosphates - chemistry Preparations and properties |
| title | Catalytic Dealkylation of Phosphates with Binuclear Boron Compounds |
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