The interaction of water and dibromine in the gas phase: an investigation of the complex H(2)O...Br(2) by rotational spectroscopy and ab initio calculations

The ground-state rotational spectra of eight isotopomers of a complex formed by water and dibromine in the gas phase were observed by pulsed-jet, Fourier transform microwave spectroscopy. The spectroscopic constants B(0), C(0), delta(J), delta(JK), chi(aa)(Br(x)) (x=i for inner, o for outer), [chi(b...

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Veröffentlicht in:Chemistry : a European journal 2002-02, Vol.8 (4), p.940-950
Hauptverfasser: Legon, Anthony C, Thumwood, Jennifer M A, Waclawik, Eric R
Format: Artikel
Sprache:eng
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