Strain and Reactivity: Electrophilic Addition of Bromine and Tribromide Salts to Cyclic Allenes

The kinetics and the products of the bromination of several cyclic allenes, from C9 to C13 (1 a–e), with tetrabutylammonium tribromide (TBAT) and Br2 have been investigated in 1,2‐dichloroethane (DCE) and methanol. The first product of the interaction between the allene and Br2 is a 1:1 π complex. T...

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Veröffentlicht in:	Chemistry : a European journal 2002-02, Vol.8 (4), p.967-978
Hauptverfasser:	Chiappe, Cinzia, De Rubertis, Antonietta, Detert, Heiner, Lenoir, Dieter, Wannere, Chaitanya S., Schleyer, Paul von R.
Format:	Artikel
Sprache:	eng
Schlagworte:	allenes bromination charge-transfer complex electrophilic addition reaction mechanisms steric strain
Online-Zugang:	Volltext
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