Kinetics of Aquation and Anation of Ruthenium(II) Arene Anticancer Complexes, Acidity and X-ray Structures of Aqua Adducts

The aqua adducts of the anticancer complexes [(η6‐X)Ru(en)Cl][PF6] (X=biphenyl (Bip) 1, X=5,8,9,10‐tetrahydroanthracene (THA) 2, X=9,10‐dihydroanthracene (DHA) 3; en=ethylenediamime) were separated by HPLC and characterised by mass spectrometry as the products of hydrolysis in water. The X‐ray struc...

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