Deactivation Behavior and Excited-State Properties of (Coumarin-4-yl)methyl Derivatives. 2. Photocleavage of Selected (Coumarin-4-yl)methyl-Caged Adenosine Cyclic 3‘,5‘-Monophosphates with Fluorescence Enhancement

A series of axial and equatorial diastereomers of (coumarin-4-yl)methyl-caged adenosine cyclic 3‘,5‘-monophosphates (cAMPs), 1 − 6, having methoxy, dialkylamino, or no substituent in the 6- and/or 7-positions, and their corresponding 4-(hydroxymethyl)coumarin photoproducts 7 − 12 have been synthesiz...

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Veröffentlicht in:	Journal of organic chemistry 2002-02, Vol.67 (3), p.703-710
Hauptverfasser:	Eckardt, Torsten, Hagen, Volker, Schade, Björn, Schmidt, Reinhardt, Schweitzer, Claude, Bendig, Jürgen
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbohydrates. Nucleosides and nucleotides Chemistry Coumarins - chemistry Cyclic AMP - analogs & derivatives Cyclic AMP - chemistry Exact sciences and technology Fluorescence Nucleosides, nucleotides and oligonucleotides Organic chemistry Photochemistry Preparations and properties Spectrometry, Fluorescence Spectrometry, Mass, Electrospray Ionization Spectrophotometry, Ultraviolet
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