The 5-V Window of Polarizability of Fluorinated Diamond Electrodes in Aqueous Solutions
Heavily doped diamond films are quite actively studied for their promising applications in industrial as well as in fundamental electrochemistry (both for physicochemical studies and in the field of electroanalysis), because of their very high stability toward chemical and electrochemical oxidative...
Gespeichert in:
| Veröffentlicht in: | Analytical chemistry (Washington) 2003-12, Vol.75 (24), p.7040-7042 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 7042 |
|---|---|
| container_issue | 24 |
| container_start_page | 7040 |
| container_title | Analytical chemistry (Washington) |
| container_volume | 75 |
| creator | Ferro, Sergio De Battisti, Achille |
| description | Heavily doped diamond films are quite actively studied for their promising applications in industrial as well as in fundamental electrochemistry (both for physicochemical studies and in the field of electroanalysis), because of their very high stability toward chemical and electrochemical oxidative attacks. Fluorinated diamond electrodes exhibit an exceptionally lower electrocatalytic activity toward reactions involving adsorbed intermediates, as a result of the F-termination of the surface dangling bonds. This feature allows the investigation of the widest range of potentials for an electrode material in aqueous solution, being limited only by the formation of free hydrogen [E° (H•/H2) = −2.3 VSHE] and hydroxyl [E° (•OH,H+/H2O) = 2.74 VSHE] radicals, at the two boundaries of the ∼5-V polarization window. |
| doi_str_mv | 10.1021/ac034717r |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_71449601</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>549239661</sourcerecordid><originalsourceid>FETCH-LOGICAL-a472t-e947edbb1b4bba3f12023f0ebe8c62ec5820e31f2d91e58c797d7063640e21393</originalsourceid><addsrcrecordid>eNpl0NFqFDEUBuAgil1bL3wBCYKCF9Oek2SSmcuydqtQ6EpXK96ETCaDqdlJm8zQ1qd3ll26oFeBk4_Df35C3iAcIzA8MRa4UKjSMzLDkkEhq4o9JzMA4AVTAAfkVc43AIiA8iU5QCGnqYIZuV79crQsvtNr37fxnsaOLmMwyf8xjQ9-eNxMFmGMyfdmcC395M069i09C84OKbYuU9_T07vRxTHTqxjGwcc-H5EXnQnZvd69h-Tb4mw1_1xcXJ5_mZ9eFEYoNhSuFsq1TYONaBrDO2TAeAeucZWVzNmyYuA4dqyt0ZWVVbVqFUguBTiGvOaH5MN2722KU4Y86LXP1oVg-k0grVCIWgJO8N0_8CaOqZ-yaYaqklJiOaGPW2RTzDm5Tt8mvzbpUSPoTdX6qerJvt0tHJu1a_dy1-0E3u-AydaELpne-rx3JVeCQTW5Yut8HtzD079Jv7VUXJV6tbzSP5bwdTHn5_rnfq-xeX_E_wH_Aqnun6M</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>217866615</pqid></control><display><type>article</type><title>The 5-V Window of Polarizability of Fluorinated Diamond Electrodes in Aqueous Solutions</title><source>ACS Publications</source><creator>Ferro, Sergio ; De Battisti, Achille</creator><creatorcontrib>Ferro, Sergio ; De Battisti, Achille</creatorcontrib><description>Heavily doped diamond films are quite actively studied for their promising applications in industrial as well as in fundamental electrochemistry (both for physicochemical studies and in the field of electroanalysis), because of their very high stability toward chemical and electrochemical oxidative attacks. Fluorinated diamond electrodes exhibit an exceptionally lower electrocatalytic activity toward reactions involving adsorbed intermediates, as a result of the F-termination of the surface dangling bonds. This feature allows the investigation of the widest range of potentials for an electrode material in aqueous solution, being limited only by the formation of free hydrogen [E° (H•/H2) = −2.3 VSHE] and hydroxyl [E° (•OH,H+/H2O) = 2.74 VSHE] radicals, at the two boundaries of the ∼5-V polarization window.</description><identifier>ISSN: 0003-2700</identifier><identifier>EISSN: 1520-6882</identifier><identifier>DOI: 10.1021/ac034717r</identifier><identifier>PMID: 14670070</identifier><identifier>CODEN: ANCHAM</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Analytical chemistry ; Aqueous solutions ; Chemistry ; Diamonds ; Electrochemical methods ; Electrodes ; Exact sciences and technology ; Fluorescence</subject><ispartof>Analytical chemistry (Washington), 2003-12, Vol.75 (24), p.7040-7042</ispartof><rights>Copyright © 2003 American Chemical Society</rights><rights>2004 INIST-CNRS</rights><rights>Copyright American Chemical Society Dec 15, 2003</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a472t-e947edbb1b4bba3f12023f0ebe8c62ec5820e31f2d91e58c797d7063640e21393</citedby><cites>FETCH-LOGICAL-a472t-e947edbb1b4bba3f12023f0ebe8c62ec5820e31f2d91e58c797d7063640e21393</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ac034717r$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ac034717r$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2751,27055,27903,27904,56716,56766</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15374208$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/14670070$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ferro, Sergio</creatorcontrib><creatorcontrib>De Battisti, Achille</creatorcontrib><title>The 5-V Window of Polarizability of Fluorinated Diamond Electrodes in Aqueous Solutions</title><title>Analytical chemistry (Washington)</title><addtitle>Anal. Chem</addtitle><description>Heavily doped diamond films are quite actively studied for their promising applications in industrial as well as in fundamental electrochemistry (both for physicochemical studies and in the field of electroanalysis), because of their very high stability toward chemical and electrochemical oxidative attacks. Fluorinated diamond electrodes exhibit an exceptionally lower electrocatalytic activity toward reactions involving adsorbed intermediates, as a result of the F-termination of the surface dangling bonds. This feature allows the investigation of the widest range of potentials for an electrode material in aqueous solution, being limited only by the formation of free hydrogen [E° (H•/H2) = −2.3 VSHE] and hydroxyl [E° (•OH,H+/H2O) = 2.74 VSHE] radicals, at the two boundaries of the ∼5-V polarization window.</description><subject>Analytical chemistry</subject><subject>Aqueous solutions</subject><subject>Chemistry</subject><subject>Diamonds</subject><subject>Electrochemical methods</subject><subject>Electrodes</subject><subject>Exact sciences and technology</subject><subject>Fluorescence</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNpl0NFqFDEUBuAgil1bL3wBCYKCF9Oek2SSmcuydqtQ6EpXK96ETCaDqdlJm8zQ1qd3ll26oFeBk4_Df35C3iAcIzA8MRa4UKjSMzLDkkEhq4o9JzMA4AVTAAfkVc43AIiA8iU5QCGnqYIZuV79crQsvtNr37fxnsaOLmMwyf8xjQ9-eNxMFmGMyfdmcC395M069i09C84OKbYuU9_T07vRxTHTqxjGwcc-H5EXnQnZvd69h-Tb4mw1_1xcXJ5_mZ9eFEYoNhSuFsq1TYONaBrDO2TAeAeucZWVzNmyYuA4dqyt0ZWVVbVqFUguBTiGvOaH5MN2722KU4Y86LXP1oVg-k0grVCIWgJO8N0_8CaOqZ-yaYaqklJiOaGPW2RTzDm5Tt8mvzbpUSPoTdX6qerJvt0tHJu1a_dy1-0E3u-AydaELpne-rx3JVeCQTW5Yut8HtzD079Jv7VUXJV6tbzSP5bwdTHn5_rnfq-xeX_E_wH_Aqnun6M</recordid><startdate>20031215</startdate><enddate>20031215</enddate><creator>Ferro, Sergio</creator><creator>De Battisti, Achille</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7TM</scope><scope>7U5</scope><scope>7U7</scope><scope>7U9</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H94</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>20031215</creationdate><title>The 5-V Window of Polarizability of Fluorinated Diamond Electrodes in Aqueous Solutions</title><author>Ferro, Sergio ; De Battisti, Achille</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a472t-e947edbb1b4bba3f12023f0ebe8c62ec5820e31f2d91e58c797d7063640e21393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Analytical chemistry</topic><topic>Aqueous solutions</topic><topic>Chemistry</topic><topic>Diamonds</topic><topic>Electrochemical methods</topic><topic>Electrodes</topic><topic>Exact sciences and technology</topic><topic>Fluorescence</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ferro, Sergio</creatorcontrib><creatorcontrib>De Battisti, Achille</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical chemistry (Washington)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ferro, Sergio</au><au>De Battisti, Achille</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The 5-V Window of Polarizability of Fluorinated Diamond Electrodes in Aqueous Solutions</atitle><jtitle>Analytical chemistry (Washington)</jtitle><addtitle>Anal. Chem</addtitle><date>2003-12-15</date><risdate>2003</risdate><volume>75</volume><issue>24</issue><spage>7040</spage><epage>7042</epage><pages>7040-7042</pages><issn>0003-2700</issn><eissn>1520-6882</eissn><coden>ANCHAM</coden><abstract>Heavily doped diamond films are quite actively studied for their promising applications in industrial as well as in fundamental electrochemistry (both for physicochemical studies and in the field of electroanalysis), because of their very high stability toward chemical and electrochemical oxidative attacks. Fluorinated diamond electrodes exhibit an exceptionally lower electrocatalytic activity toward reactions involving adsorbed intermediates, as a result of the F-termination of the surface dangling bonds. This feature allows the investigation of the widest range of potentials for an electrode material in aqueous solution, being limited only by the formation of free hydrogen [E° (H•/H2) = −2.3 VSHE] and hydroxyl [E° (•OH,H+/H2O) = 2.74 VSHE] radicals, at the two boundaries of the ∼5-V polarization window.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>14670070</pmid><doi>10.1021/ac034717r</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0003-2700 |
| ispartof | Analytical chemistry (Washington), 2003-12, Vol.75 (24), p.7040-7042 |
| issn | 0003-2700 1520-6882 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_71449601 |
| source | ACS Publications |
| subjects | Analytical chemistry Aqueous solutions Chemistry Diamonds Electrochemical methods Electrodes Exact sciences and technology Fluorescence |
| title | The 5-V Window of Polarizability of Fluorinated Diamond Electrodes in Aqueous Solutions |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T08%3A12%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%205-V%20Window%20of%20Polarizability%20of%20Fluorinated%20Diamond%20Electrodes%20in%20Aqueous%20Solutions&rft.jtitle=Analytical%20chemistry%20(Washington)&rft.au=Ferro,%20Sergio&rft.date=2003-12-15&rft.volume=75&rft.issue=24&rft.spage=7040&rft.epage=7042&rft.pages=7040-7042&rft.issn=0003-2700&rft.eissn=1520-6882&rft.coden=ANCHAM&rft_id=info:doi/10.1021/ac034717r&rft_dat=%3Cproquest_cross%3E549239661%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=217866615&rft_id=info:pmid/14670070&rfr_iscdi=true |