Self-Assembled Nanotubes that Reversibly Bind Acetic Acid Guests

A large bis-urea macrocycle was synthesized and assembled into columnar nanotubes containing a sizable cavity. This purely organic nanotube is held together primarily by hydrogen bonding and yet shows remarkable thermal stability up to 180 °C in the presence and absence of acetic acid guest. This en...

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Veröffentlicht in:Journal of the American Chemical Society 2003-12, Vol.125 (49), p.14972-14973
Hauptverfasser: Shimizu, Linda S, Hughes, Andrew D, Smith, Mark D, Davis, Matthew J, Zhang, B. Paul, zur Loye, Hans-Conrad, Shimizu, Ken D
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container_end_page 14973
container_issue 49
container_start_page 14972
container_title Journal of the American Chemical Society
container_volume 125
creator Shimizu, Linda S
Hughes, Andrew D
Smith, Mark D
Davis, Matthew J
Zhang, B. Paul
zur Loye, Hans-Conrad
Shimizu, Ken D
description A large bis-urea macrocycle was synthesized and assembled into columnar nanotubes containing a sizable cavity. This purely organic nanotube is held together primarily by hydrogen bonding and yet shows remarkable thermal stability up to 180 °C in the presence and absence of acetic acid guest. This enables the nanotube to be used as reusable organic zeolite.
doi_str_mv 10.1021/ja036515i
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source ACS Publications; MEDLINE
subjects Acetic Acid - chemistry
Cross-disciplinary physics: materials science
rheology
Crystallography, X-Ray
Exact sciences and technology
Hydrogen Bonding
Magnetic Resonance Spectroscopy
Materials science
Molecular Structure
Nanotubes - chemistry
New materials: theory, design, and fabrication
Other materials
Physics
Specific materials
Urea - analogs & derivatives
Urea - chemistry
title Self-Assembled Nanotubes that Reversibly Bind Acetic Acid Guests
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