Biomimetic Synthesis of (−)-Longithorone A

An enantioseletive, biomimetic synthesis of (−)-longithorone A has been achieved using an intermolecular/transannular Diels-Alder sequence which provides some support for the proposed biosynthesis. The cycloaddition precursors were two [12]-paracyclophanes that were constructed with atropisomer cont...

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Veröffentlicht in:	Journal of the American Chemical Society 2002-02, Vol.124 (5), p.773-775
Hauptverfasser:	Layton, Mark E, Morales, Carl A, Shair, Matthew D
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Biological Factors - chemical synthesis Bridged-Ring Compounds - chemical synthesis Chemistry Exact sciences and technology Molecular Mimicry Organic chemistry Polycyclic Compounds - chemical synthesis Preparations and properties Stereoisomerism
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